Local-Site Dependency of Magneto-Chiral Dichroism in Enantiopure One-Dimensional Copper(II)-Chromium(III) Coordination Polymers

摘要

Magneto-chiral dichroism (MChD) is a nonreciprocal directional dichroism emerged by applying a magnetic field to chiral materials, which provides a clear distinction between light propagating parallel and antiparallel to the magnetic-field direction. So far the correlation between the metal origin magnetization and MChD signal has been reported in homometallic complexes bearing chiral ligands, but that in hetero-metal systems with short-range correlations has never been investigated. Here, we demonstrate that MChD in d-d transitions of Cu-II bearing chiral ligands in an cyano-bridged copper(II) -chromium(M) chain is mainly proportional to the magnetization of local Cu-II center, which involves intraatomic transition, rather than to the ferromagnetically correlated spin magnetization.