Clay Swelling Inhibition Using Novel Cationic Gemini Surfactants with Different Spacers

摘要

Hydration of shale formation by water-based drilling fluids leads to several problems, such as the collapse of boreholes, tight holes, and stuck pipe, which may impede further drilling and time loss in rectifying the problems, leading to heavy economic losses. This study reports the development of new gemini cationic surfactants as shale-swelling inhibitors. These gemini surfactants are structurally similar but differ in terms of the spacer group. Saturated butyl group (GS1) and unsaturated 2-butenyl (GS2) and 2-butynyl (GS3) were introduced as spacer groups of gemini surfactants. To assess the performance of new gemini cationic surfactants, two reliable clay sources were considered. The first clay is from an unconventional formation and the second clay is sodium bentonite. The inhibition characteristics of gemini surfactants were evaluated using dynamic swelling, hot rolling, rheology, and filtration experiments. Different formulations based on commercially available solutions for shale-swelling inhibitors were applied and compared with cationic shale inhibitors. It was observed that the new gemini cationic surfactants with different spacers (saturated and unsaturated) reduced the shale swelling by different percentages. The GS2 surfactant, containing an unsaturated double bond proved to be a good swelling inhibitor as compared to GS1 and GS3. It also showed acceptable performance compared with the common shale inhibitor (KCl) used in the industry. The addition of surfactant has less impact on the rheological properties as compared to KCl. The filtration properties of the base mud were unchanged when surfactants were used. However, the commercial inhibitor, KCl, significantly increased the filtration volume that is associated with the disintegration of the clay. In summary, unlike commercial inhibitors, the synthesized surfactants reduced the clay swelling without affecting the other properties of the drilling fluids.