Vibrational spectra of the rare‐occurring complex hydrogen arsenate minerals pharmacolite, picropharmacolite, and vladimirite: Dominance of RR aman over IRIR spectroscopy to discriminate arsenate and hydrogen arsenate units

机译：珍稀富含氢气砷盐的振动光谱parmacolite，picropharmolite和vladimirite： r r aman over IR IR光谱，以区分砷酸和氢砷酸酯单位

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Abstract > This work represents the first complete experimental and theoretical study of the infrared (IR) spectra of pharmacolite, Ca(AsO <sub>3</sub> OH)·2H <sub>2</sub> O; vladimirite, Ca <sub>4</sub> (AsO <sub>3</sub> OH)(AsO <sub>4</sub> ) <sub>2</sub> ·4H <sub>2</sub> O; and picropharmacolite, Ca <sub>4</sub> Mg(AsO <sub>3</sub> OH) <sub>2</sub> (AsO <sub>4</sub> ) <sub>2</sub> ·11H <sub>2</sub> O. IR spectra, collected at both room and liquid nitrogen temperature, have shown similar spectral view among minerals in the region of ν <sub>1</sub> to ν <sub>4</sub> modes, surprisingly not involving complexity in vladimirite and picropharmacolite spectral view due to the presence of both AsO <sub>3</sub> OH and AsO <sub>4</sub> units compared to pharmacolite where only AsO <sub>3</sub> OH units appear in the structure. On the other hand, vladimirite and picropharmacolite Raman spectra in the corresponding ν <sub>1</sub> to ν <sub>4</sub> region (955–350?cm ?1 ) exhibit existence of 3 sets of 2 bands (6 in total) completely reflecting the existence of 3 symmetrically nonequivalent AsO <sub>4</sub> groups in the structures of vladimirite and picropharmacolite (of which one is protonated) and only one set of ν <sub>1</sub> to ν <sub>4</sub> bands from the structurally equivalent AsO <sub>3</sub> OH units in the pharmacolite structure. The liquid nitrogen temperature IR spec </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >这项工作代表Pharacolite的红外（IR）光谱的第一个完整的实验和理论研究，Ca（AS0 <sub> 3 </ sub）·2H <sub> 2 </ sub> O; Vladimirite，CA <sub> 4 </ sub>（ASO <sub> 3 </ sub> OH）（ASO <sub> 4 </ sub>）<sub> 2 </ sub>·4h <sub> 2 </ sub> o;和Picropharmogolite，Ca <sub> 4 </ sub> mg（ASO <sub> 3 </ sub> OH）<sub> 2 </ sub>（ASO <sub> 4 </ sub>）<sub> 2 </在空间和液氮温度下收集的亚>·11H <亚> 2 </ sub> O. IR光谱在ν<sub> 1 <sub>到ν<sub的区域中，矿物质中的矿物质相似。 > 4个</ sub>模式，令人惊讶的是，由于ASO <sub> 3 </ sub> OH和ASO <sub> 4 </ sub>单位仅与Pharmacolite相比，vladimirite和Picrophararmolite光谱视图中的复杂性。 ASO <sub> 3 </ sub> OH单位出现在结构中。另一方面，vladimirite和Picropharmacolite拉曼光谱在相应的ν<sub> 1 </ sub>到ν<sub> 4 </ sub>区域（955-350°CM 1 </ sup>）展示存在3组2条带（总共6个）完全反映了vladimirite和Picropharmopharite结构中的3个对称非等级Aso <sub> 4 </ sub>组的存在（其中一个被质子），只有一组ν <sub> 1 </ sub>到ν<sub> 4 </ sub>频带来自药狼结构中的结构等同的aso <sub> 3 </ sub> OH单元。液氮温度IR规格 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35645/'>《Journal of Raman Spectroscopy: An International Journal for Original Work in All Aspects of Raman Spectroscopy, Including Higher Order Processes, and Also Brillouin- and Rayleigh Scattering》</a> <b style="margin: 0 2px;">|</b><span>2018年第4期</span><b style="margin: 0 2px;">|</b><span>共17页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Makreski Petre&option=202" target="_blank" rel="nofollow">Makreski Petre;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Todorov Jovica&option=202" target="_blank" rel="nofollow">Todorov Jovica;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Makrievski Vasil&option=202" target="_blank" rel="nofollow">Makrievski Vasil;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pejov Ljup?o&option=202" target="_blank" rel="nofollow">Pejov Ljup?o;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jovanovski Gligor&option=202" target="_blank" rel="nofollow">Jovanovski Gligor;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Chemistry Faculty of Natural Sciences and MathematicsSs. Cyril and Methodius UniversityArhimedova 5 1000 Skopje Republic of Macedonia;</p> <p>Institute of Chemistry Faculty of Natural Sciences and MathematicsSs. Cyril and Methodius UniversityArhimedova 5 1000 Skopje Republic of Macedonia;</p> <p>Institute of Chemistry Faculty of Natural Sciences and MathematicsSs. Cyril and Methodius UniversityArhimedova 5 1000 Skopje Republic of Macedonia;</p> <p>Institute of Chemistry Faculty of Natural Sciences and MathematicsSs. Cyril and Methodius UniversityArhimedova 5 1000 Skopje Republic of Macedonia;</p> <p>Institute of Chemistry Faculty of Natural Sciences and MathematicsSs. Cyril and Methodius UniversityArhimedova 5 1000 Skopje Republic of Macedonia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4724.html" title="光谱学">光谱学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=arsenate minerals&option=203" rel="nofollow">arsenate minerals;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen arsenates&option=203" rel="nofollow">hydrogen arsenates;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen bonding&option=203" rel="nofollow">hydrogen bonding;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=quantum theoretical methods&option=203" rel="nofollow">quantum theoretical methods;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=vibrational spectroscopy&option=203" rel="nofollow">vibrational spectroscopy;</a> </p> <div class="translation"> 机译：砷化物矿物;氢气砷;氢键;量子理论方法;振动光谱; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025815098.html">Vibrational spectra of the rare‐occurring complex hydrogen 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