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On the Timescale of Magma Ocean Solidification and Its Chemical Consequences: 1. Thermodynamic Database for Liquid at High Pressures

机译：关于岩浆海洋凝固的时间尺度及其化学后果：1。高压液体热力学数据库

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Abstract > We present a new method to construct an internally consistent thermodynamic model using a compilation of high‐pressure melting experiments. The steepest descent method and Monte Carlo sampling are combined to constrain all model parameters simultaneously instead of determining each parameter sequentially from relevant experiments. Our approach is applied to the published melting experiments on mantle materials to obtain the thermodynamic parameters of the MgO‐FeO‐SiO <sub>2</sub> ternary system. Inversion with the subsets of experimental data is conducted as well to investigate the source of discrepancy among existing studies, and the key parameters are found to be the thermal expansivity of SiO <sub>2</sub> and the excess volume of mixing between MgO and SiO <sub>2</sub> . Mixing between FeO and SiO <sub>2</sub> is only constrained with large uncertainty, which could also imply that oxides with low concentrations have minimal effects on melting. Constraining the thermodynamics of MgO and SiO <sub>2</sub> will be important for a better understanding of mantle melting at high pressures. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”XML：ID =“JGRB53378-ABS-ABS-ABS-ABS-ABS-0001”> <标题类型=“main”>抽象</ title> >我们提出了一种构造一个新方法内部一致的热力学模型使用高压熔化实验的汇编。最陡的下降方法和蒙特卡罗采样组合以同时约束所有模型参数，而不是从相关实验中顺序确定每个参数。我们的方法适用于披风材料上发表的熔化实验，以获得MgO-Feo-SiO <Sub> 2 </ sub>三元系统的热力学参数。对实验数据的子集进行反转，也进行了研究现有研究的差异来源，并且发现关键参数是SiO <sub> 2 </ sub>的热膨胀性，以及MgO之间的混合体积的过量混合和sio <sub> 2 </ sub>。在FeO和SiO <sub> 2之间混合仅受到大的不确定性的限制，这也可能意味着具有低浓度的氧化物对熔化具有最小的影响。约束MgO和SiO <sub> 2 </ sub>的热力学对于更好地了解高压下的米兰熔化是重要的。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-34677/'>《Journal of geophysical research. Solid earth: JGR》</a> <b style="margin: 0 2px;">|</b><span>2019年第4期</span><b style="margin: 0 2px;">|</b><span>共17页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Miyazaki Yoshinori&option=202" target="_blank" rel="nofollow">Miyazaki Yoshinori;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Korenaga Jun&option=202" target="_blank" rel="nofollow">Korenaga Jun;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Geology and GeophysicsYale UniversityNew Haven CT USA;</p> <p>Department of Geology and GeophysicsYale UniversityNew Haven CT USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/163.html" title="地球物理学">地球物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=magma ocean&option=203" rel="nofollow">magma ocean;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=high pressure melting&option=203" rel="nofollow">high pressure melting;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thermodynamics&option=203" rel="nofollow">thermodynamics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=data analysis&option=203" rel="nofollow">data analysis;</a> </p> <div class="translation"> 机译：岩浆海洋;高压熔化;热力学;数据分析; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025591592.html">On the Timescale of Magma Ocean Solidification and Its Chemical Consequences: 1. 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Procedures for producing containers of various liquids, new annular procedures with various liquids, new annular procedures with various pressures, or applications of known containers.</a> <b>[P]</b> . <span> 外国专利：  ES50357A2 </span> <span> . 1911-07-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：1.生产各种液体的容器的程序，具有各种液体的新的环形程序，具有各种压力的新的环形程序或已知容器的应用。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130450043086.html">Solving statistic thermodynamic in group contribution method for predicting thermodynamic properties of liquid mixtures and chemical substances involves determining molecular-fragment specific activity coefficients</a> <b>[P]</b> . <span> 外国专利：  DE19912152A1 </span> <span> . 2000-09-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：求解集体贡献法中的统计热力学以预测液体混合物和化学物质的热力学性质，涉及确定分子片段比活度系数 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130498857517.html">1. A chemical process for manufacturing a new type of industrial chemicals, including a fresh liquid called espander.</a> <b>[P]</b> . <span> 外国专利：  ES28173A2 </span> <span> . 1901-09-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：1.一种用于制造新型工业化学品的化学过程，包括一种称为“ espander”的新鲜液体。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704025591592','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704025591592down" data-source="7," data-out-id="R4lQtpRjZWqreXi5CPwWlvWSA3Wt6IjVOHJlMJb3y2M+xMcML+zvM8K380rAHGls," data-f-source-id="7" data-title="On the Timescale of Magma Ocean Solidification and Its Chemical Consequences: 1. 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