Toward a Robust Elastic Geobarometry of Kyanite Inclusions in Eclogitic Diamonds

Nestola F.; Prencipe M.; Nimis P.; Sgreva N.; Perritt S. H.; Chinn I. L.; Zaffiro G.

摘要

Abstract > Here we report the first results from elastic geobarometry applied to a kyanite inclusion entrapped within an eclogitic diamond (from Voorspoed mine, South Africa) using micro‐Raman and Fourier transform infrared spectroscopy, electron microprobe analysis, ab initio calculations, and finite element modeling. Application of elastic geobarometry to very elastically anisotropic kyanite inclusions is challenging, as current models do not allow for elastic anisotropy. In order to minimize the effects of anisotropy, we have explored the effects of deviatoric stress on Raman modes via ab initio density functional theory. The results allowed us to select the Raman mode (at ca. 638?cm ?1 ) that is the least sensitive to deviatoric stress. The shift of this band in the inclusion while still trapped within the diamond relative to the inclusion in air (once liberated) was used under hydrostatic approximation to determine a residual pressure on the inclusion of 0.184?±?0.045?GPa and an entrapment pressure of 5.2?±?0.3?GPa (~160?km depth) for an FTIR N‐aggregation residence temperature of 1119?±?50?°C. This is the first geothermobarometric determination for a diamond from the Voorspoed kimberlite. It overlaps with P–T estimates obtained by traditional chemical geobarometry for diamonds from other kimberlites from the Kaapvaal craton, suggesting that the hydrostatic approximation does not introduce significant errors in the geobarometric evaluation. Our protocol of Raman peak selection can be used for geobarometry of further kyanite‐bearing diamonds and may provide a guide for more robust geobarometry of other types of mineral inclusions in diamonds, both eclogitic and peridotitic. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >在这里，我们报告了应用于捕获在eClogitic钻石中的kyanite包装的弹性地质测量术中的第一个结果（来自佛罗里达矿，南非）使用微拉曼和傅里叶变换红外光谱，电子微探针分析，AB Initio计算和有限元建模。弹性地理仪在非常弹性的各向异性苯基石夹杂物的应用是具有挑战性的，因为目前的模型不允许弹性各向异性。为了最大限度地减少各向异性的影响，我们通过AB Initio密度函数理论探讨了偏离偏移压力对拉曼模式的影响。结果允许我们选择拉曼模式（在约638？cm ？1 </ sup>）对偏差应力最不敏感。在静水近似下使用相对于空气中的包含在空气中的夹杂物内的夹杂物内的夹杂物的偏移在静水近似下使用，以确定剩余压力为0.184≤0.045≤0.045？GPA和夹紧压力5.2？±±0.3？GPA（〜160×km深度），用于1119〜±50Ω·°C的FTIR N-聚集停留温度。这是来自育植物的金刚石的第一个地热磁性测量测定。它与来自来自Kaapvaal Craton的其他金伯拉特的传统化学地质测定法获得的估计与来自Kaapvaal Craton的其他金刚石的估计重叠，这表明静液压近似不会在地质测量评估中引入重大误差。我们的拉曼峰值选择的协议可用于进一步含有kyanite钻石的地质测量仪，并可提供更强大的植物中其他类型的矿物质夹杂物的引导术，葡萄酒和偏见。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-34677/'>《Journal of geophysical research. Solid earth: JGR》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nestola F.&option=202" target="_blank" rel="nofollow">Nestola F.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Prencipe M.&option=202" target="_blank" rel="nofollow">Prencipe M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nimis P.&option=202" target="_blank" rel="nofollow">Nimis P.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sgreva N.&option=202" target="_blank" rel="nofollow">Sgreva N.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Perritt S. H.&option=202" target="_blank" rel="nofollow">Perritt S. H.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chinn I. L.&option=202" target="_blank" rel="nofollow">Chinn I. L.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zaffiro G.&option=202" target="_blank" rel="nofollow">Zaffiro G.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Dipartimento di GeoscienzeUniversità degli Studi di PadovaPadova Italy;</p> <p>Dipartimento di Scienze della TerraUniversità degli Studi di TorinoTorino Italy;</p> <p>Dipartimento di GeoscienzeUniversità degli Studi di PadovaPadova Italy;</p> <p>Dipartimento di GeoscienzeUniversità degli Studi di PadovaPadova Italy;</p> <p>De Beers ExplorationSouthdale South Africa;</p> <p>De Beers ExplorationSouthdale South Africa;</p> <p>Dipartimento di Scienze della Terra e dell'AmbienteUniversità degli Studi di PaviaPavia Italy;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/163.html" title="地球物理学">地球物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=diamond&option=203" rel="nofollow">diamond;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=inclusion&option=203" rel="nofollow">inclusion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=kyanite&option=203" rel="nofollow">kyanite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=eclogite&option=203" rel="nofollow">eclogite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Voorspoed&option=203" rel="nofollow">Voorspoed;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=geobarometry&option=203" rel="nofollow">geobarometry;</a> </p> <div class="translation"> 机译：钻石;包含;kyanite;eglogite;voorpoed;地理测量; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025590924.html">Toward a Robust Elastic Geobarometry of Kyanite Inclusions in Eclogitic Diamonds</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nestola F.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nestola F.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Prencipe M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Prencipe M.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nimis P.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nimis P.,</a> <a href="/journal-foreign-34677/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of geophysical research. 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