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首页> 外文期刊>Journal of Chemical Technology & Biotechnology >Effect of embedded activated carbon nanoparticles on the performance of polydimethylsiloxane (PDMS) membrane for pervaporation separation of butanol
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Effect of embedded activated carbon nanoparticles on the performance of polydimethylsiloxane (PDMS) membrane for pervaporation separation of butanol

机译：嵌入式活性炭纳米粒子对丁醇渗透碘哌嗪（PDMS）膜性能的影响

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Abstract <section xml:id="jctb5306-sec-0001" numbered="no"> <title type="main">BACKGROUND >The pervaporation separation method is considered to be a promising technique for biobutanol recovery from fermentation broths. In this work, activated carbon nanoparticles were embedded in polydimethylsiloxane (PDMS) membranes to improve the pervaporation performance. </section> <section xml:id="jctb5306-sec-0002" numbered="no"> <title type="main">RESULTS > Adding 6 wt% nano‐additives in PDMS membranes increased the flux and separation factor by 42.6% and 51.9%, respectively, compared with neat membranes at 37°C. Enhanced performance is due to: 1 the presence of additional sorption sites within the membrane with a high affinity for butanol; and 2 the porous structure of the nanofillers generate new pathways for facilitated mass transport through the membrane. The effect of the operating temperature and particle concentration on membrane performance was investigated. Membrane performance improved with an increase in the operating temperature. Higher temperature resulted in increased free volume in the PDMS chains leading to higher diffusion of butanol. Mechanical tensile tests showed that nanocomposite membranes have better mechanical stability in comparison with neat PDMS membranes with the best performance observed at 6 wt% of the nano‐additives. </section> <section xml:id="jctb5306-sec-0003" numbered="no"> <title type="main">CONCLUSION >The presence of activated carbon nanoparticles in the matrix of PDMS membranes leading to higher flux and separation factor can be beneficial for pervaporation separation of butanol from fermentation broths. ? 2017 Society of C </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract xmlns =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>抽象</ title> <section XML：ID =“JCTB5306-SEC-0001 “编号=”否“> <标题类型=”main“>背景</标题> >普及分离方法被认为是从发酵肉汤中恢复生物丁醇的有希望的技术。在这项工作中，将活性炭纳米颗粒嵌入聚二甲基硅氧烷（PDMS）膜中以改善渗透性的性能。</ p> </ section> <章节XML：ID =“JCTB5306-SEC-0002”编号为“否”> <标题类型=“Main”>结果</标题> <P>在PDMS膜中加入6wt％纳米添加剂，分别增加了42.6％和51.9％，与37℃的纯膜相比。增强的性能是由于： 1 </ sup>膜内的额外吸附位点，对丁醇具有高亲和力;和 2 </ sup>纳米填料的多孔结构产生通过膜的促进质量传输的新途径。研究了操作温度和颗粒浓度对膜性能的影响。膜性能随着工作温度的增加而改善。较高的温度导致PDMS链中的自由体积增加，导致丁醇的较高扩散。机械拉伸试验表明，纳米复合材料膜具有更好的机械稳定性，与整齐的PDMS膜相比，在6wt％的纳米添加剂中观察到的最佳性能。 </ p> </ section> <section XML：ID =“JCTB5306-SEC-0003”编号=“否”> <标题类型=“MAIN”>结论</标题> <P>存在活性炭纳米粒子的存在PDMS膜的基质导致较高的助焊剂和分离因子可以是有益于发酵肉汤的蛋白丁醇的渗透分离。还2017年度社会 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33908/'>《Journal of Chemical Technology & Biotechnology》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Azimi Hoda&option=202" target="_blank" rel="nofollow">Azimi Hoda;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tezel F Handan&option=202" target="_blank" rel="nofollow">Tezel F Handan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thibault Jules&option=202" target="_blank" rel="nofollow">Thibault Jules;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemical and Biological EngineeringUniversity of OttawaOttawa Ontario Canada;</p> <p>Department of Chemical and Biological EngineeringUniversity of OttawaOttawa Ontario Canada;</p> <p>Department of Chemical and Biological EngineeringUniversity of OttawaOttawa Ontario Canada;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/180.html" title="生物工程学（生物技术）">生物工程学（生物技术）;</a><a href="https://www.zhangqiaokeyan.com/clc/20827.html" title="生物化学过程">生物化学过程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=biobutanol&option=203" rel="nofollow">biobutanol;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pervaporation&option=203" rel="nofollow">pervaporation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mixed matrix membrane&option=203" rel="nofollow">mixed matrix membrane;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=PDMS&option=203" rel="nofollow">PDMS;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=activated carbon nanoparticles&option=203" rel="nofollow">activated carbon nanoparticles;</a> </p> <div class="translation"> 机译：Biobutanol;渗透蒸发;混合基质膜;PDMS;活性炭纳米粒子; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a 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<span> <a href="/journal-cn-13389/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 粘接 </a> </span> <span> . 2018</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-12109_thesis/02022557635.html">支撑层对PDMS复合膜渗透汽化优先透醇性能的影响</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=展侠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 展侠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韩小龙&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,韩小龙</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=樊铖&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,樊铖</a> <span> <a href="/conference-cn-12109/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第四届中国膜科学与技术报告会 </a> <span> <span> . 2010</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316293441.html">MAF--6丁醇吸附与PDMS基膜渗透汽化性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=关沛雯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 关沛雯</a> <span> . 2021</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06130419173615.html">Membrane, useful in filter module for gas separation, comprises copolymer matrix, and nanoparticles embedded into matrix, where nanoparticles comprise single-walled carbon nano-tubes that are homogeneously distributed in copolymer matrix</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE102011082830A1 </span> <span> . 2013-03-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在用于气体分离的过滤器模块中有用的膜包括共聚物基质和嵌入基质中的纳米颗粒，其中纳米颗粒包含均匀分布在共聚物基质中的单壁碳纳米管 </span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06130499766104.html">Method for the Preparation of High Performance Pervaporation Membranes Using Functional Crosslinkers for Butanol Recovery</a> <b>[P]</b> . <span> 外国专利： <!-- --> KR102239805B1 </span> <span> . 2021-04-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用叔丁醇回收的功能交联剂制备高性能渗透膜的方法 </span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130441145637.html">CELLULOSE ESTER, PERVAPORATION SEPARATION MEMBRANE, PERVAPORATION SEPARATION METHOD, AND PERVAPORATION SEPARATION APPARATUS</a> <b>[P]</b> . <span> 外国专利： <!-- 日本专利： --> JP2005247935A </span> <span> . 2005-09-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：纤维素酯，渗透分离膜，渗透分离方法和渗透分离装置 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704025422689','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div 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