Indole-linked triazine-dibenzothiophene/dibenzofuran based host materials for high-efficiency green and red phosphorescent organic light-emitting diodes

摘要

Two host heterocyclic compounds 5-(dibenzo[b,d]furan-4-yl)-1-(4,6-diphenyl-1,3,5-triazin-2-yl)-1H-indole (FITRZ) and 5-(dibenzo[b,d]thiophen-4-yl)-1-(4,6-diphenyl-1,3,5-triazin-2-yl)-1H-indole (TITRZ) were synthesized by C-N coupling reaction of triazine and dibenzothiophene/dibenzofuran moiety with a 1,5-bridged indole unit. Their photo-physical, thermal and electrochemical properties were fully explored, and the results indicate that both of them are promising phosphorescent host materials for green and red PhOLED devices with low on-set potentials. For example, the green PHOLED based on TITRZ showed the maximum current and external quantum efficiency up to 85.9 cd/A and 23.7%. Meanwhile, the red PhOLED based on FITRZ yielded the maximum current and external quantum efficiency of 41.3 cd/A and 18.8% with a turn-on voltage of 3.0 V.