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Improvement of ladle slag formed in ladle metallurgy with colemanite

机译:用科尔曼矿钢包冶金形成的钢包矿渣的改进

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摘要

The ladle slag formed in ladle metallurgy (II. Metallurgy) has transportation and storage problems and it leads to environmental pollution by creating 30 million tons of waste annually in the world. Transforming this slag into a product that does not cause environmental problems would play an important role in the solution of this problem. This study has been carried out to increase the density of ladle slag which occurs in ladle metallurgy and to improve slag by converting it into a transportable by-produ1 studies were carried out in the Gebze Dilovasi facilities of Diler Iron and Steel Plant which has a production capacity of 1.300.000 tons/year of low and medium carbon steel. A transportable and denser slag has been obtained by adding colemanite in different ratios to the ladle slag, which was originally occurred in the form of [gama-dicalcium silicate gamma-Ca2(SiO4)] during cooling phase, and it is converted to [beta- dicalcium silicate beta-Ca2(SiO4)] form during the cooling. The chemical analyses, density measurements, physical analysis about slag surface appearance, chemical composition in compact points and product phase transformation analyses of the obtained slags were conducted by means of XRD and SEM/EDS devices. According to results of this study, a compact ladle slag structure was occurred by addition of colemanite and the starting ratio of B203/Slag (kg/kg) was 1%, the bulk density of the obtained slag was increased from 1.36 to 2.64 tons/m3, and a maximum 9 ppm B was industrially determined within the steel body.
机译:在钢包冶金(II。冶金)中形成的钢包渣具有运输和储存问题,并通过在世界上每年创造3000万吨垃圾来导致环境污染。将此渣转换为不会导致环境问题的产品将在解决此问题的解决方案中发挥重要作用。本研究已经开展,以提高钢包冶金发生的钢包渣密度,并通过将渣油转化为可运输的通过产品,在具有生产的Limbze Dilovasi设施中进行的研究中进行产能为1.300,000吨/年低中和中碳钢。通过在冷却阶段期间添加不同比例以不同比例的不同比例添加COLENANTE来获得可运输和密度熔渣,其在冷却阶段期间最初发生在[GAMA-DICALCIUM硅酸盐γ-CA2(SIO4)]的形式中,并将其转化为β - 冷却过程中的硅酸钠β-CA2(SiO 4)。通过XRD和SEM / EDS器件,通过XRD和SEM / EDS器件进行化学分析,密度测量,关于炉渣表面外观的物理分析,在所得炉渣中的紧凑点和产物相变分析。根据该研究的结果,通过加入CoCanite发生了一种紧凑的钢包渣结构,B203 /渣(kg / kg)的起始比率为1%,所得渣的堆积密度从1.36增加到2.64吨/ M3和最大9ppm B在钢体内工业上确定。

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