Synthesis and Energetic Properties of 1,3,7,9‐Tetranitrobenzo[c]Cinnoline‐5‐Oxide (TNBCO)

Gutowski ?ukasz; Go?ofit Tomasz; Trzciński Waldemar; Szala Mateusz

摘要

Abstract >New and efficient method for synthesis of 1,3,7,9‐tetranitrobenzo[c]cinnoline‐5‐oxide (TNBCO) via direct nitration of benzo[c]cinnoline‐5‐oxide was described. TNBCO and precursor were fully characterized by using spectroscopic (IR, NMR) and thermal analysis methods (DTA/TG). Activation energy of decomposition process was calculated by using Kissinger's equation. Standard enthalpy of formation was calculated by using experimentally determined heat of combustion. Detonation parameters were calculated with CHEETAH code and are comparable or higher than those known for E‐2,2’,4,4’,6,6’‐hexanitrostilbene (HNS) and 2,4,6‐trinitrotoluene (TNT). </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> [p>通过直接硝化苯并[C]蛋白藻氨酸-5-氧化物的合成1,3,7,9-四硝基苯[C]肉碱-5-氧化物（TNBCO）的新的和高效方法。通过使用光谱（IR，NMR）和热分析方法（DTA / TG），全部表征TNBCO和前体。通过使用基辛格的等式计算分解过程的激活能量。通过使用实验确定的燃烧热来计算地层的标准焓。用猎豹码计算爆炸参数，并且与E-2,2'，4,4'，4,4'，6,6'-己腈硅苯（HNS）和2,4,6-三硝基甲苯（TNT）的相当或高于已知的参数。< / p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2019年第12期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gutowski ?ukasz&option=202" target="_blank" rel="nofollow">Gutowski ?ukasz;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Go?ofit Tomasz&option=202" target="_blank" rel="nofollow">Go?ofit Tomasz;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Trzciński Waldemar&option=202" target="_blank" rel="nofollow">Trzciński Waldemar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Szala Mateusz&option=202" target="_blank" rel="nofollow">Szala Mateusz;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ExplosivesMilitary University of Technology2 Kaliskiego str 00-908 Warsaw Poland;</p> <p>Faculty of ChemistryWarsaw University of Technology3 Noakowskiego str 00-664 Warsaw;</p> <p>Department of ExplosivesMilitary University of Technology2 Kaliskiego str 00-908 Warsaw Poland;</p> <p>Department of ExplosivesMilitary University of Technology2 Kaliskiego str 00-908 Warsaw Poland;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=low sensitivity explosive&option=203" rel="nofollow">low sensitivity explosive;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=detonation parameters&option=203" rel="nofollow">detonation parameters;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=synthesis&option=203" rel="nofollow">synthesis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=NMR spectroscopy&option=203" rel="nofollow">NMR spectroscopy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nitration&option=203" rel="nofollow">nitration;</a> </p> <div class="translation"> 机译：低灵敏度爆炸;爆炸参数;合成;NMR光谱;硝化; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024626667.html">Synthesis and Energetic Properties of 1,3,7,9‐Tetranitrobenzo[c]Cinnoline‐5‐Oxide (TNBCO)</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gutowski ?ukasz&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gutowski ?ukasz,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Go?ofit Tomasz&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Go?ofit Tomasz,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Trzciński Waldemar&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Trzciński Waldemar,</a> <a href="/journal-foreign-29946/" target="_blank" rel="nofollow" class="tuijian_authcolor">Propellants, Explosives, Pyrotechnics .</a> <span>2019</span><span>,第12期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：1,3,7,9-四硝基苯的合成和能量特性[C]肉碱-5-氧化物（TNBCO）</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704014787930.html">The unique synthesis and energetic properties of a novel fused heterocycle: 7-nitro-4-oxo-4,8-dihydro-[1,2,4]triazolo[5,1-d][1,2,3,5]tetrazine 2-oxide and its energetic salts</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bian Chengming&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bian Chengming,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dong Xiao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dong Xiao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Xiuhui&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang Xiuhui,</a> <a href="/journal-foreign-35176/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Materials Chemistry, A. 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Synthesis andProperties of Ultrahigh Surface Area Magnesium Hydroxide and Magnesium Oxide</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Utamapanya, S.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Utamapanya, S.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Klabunde, K. J.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Klabunde, K. J.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schlup, J. R.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Schlup, J. 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