Salts of Picramic Acid – Nearly Forgotten Temperature‐Resistant Energetic Materials

Wurzenberger Maximilian H. H.; Lechner Jasmin T.; Lommel Marcus; Klap?tke Thomas M.; Stierstorfer J?rg

摘要

Abstract > Thermally stable explosives are becoming more and more important nowadays due to their important role in the oil and mining industry. The requirements of these explosives are constantly changing. Picramate‐based compounds are poorly investigated towards their energetic properties as well as sensitivities. In this work, 13 different salts of picramic acid were synthesized as potential energetic materials with high thermal stability in a simple one‐step reaction and compared with commercially used lead picramate. The obtained compounds were extensively characterized by e.?g. XRD, IR, EA, DTA, and TGA. In addition, the sensitivities towards impact and friction were determined with the BAM drop hammer and the BAM friction tester. Also, the electrostatic discharge sensitivity was explored. Calculations of the energetic performance of selected compounds were carried out with the current version of EXPLO5 code. Therefore, heats of formation were computed and X‐ray densities were converted to room temperature. Some of the synthesized salts show promising characteristics with high exothermic decomposition temperatures. Especially, the water‐free rubidium, cesium, and barium salts 5 , 6 and 10 with decomposition temperatures of almost 300?°C could be promising candidates for future applications. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 由于其在石油和采矿业中的重要作用，热稳定的炸药正在变得越来越重要。这些爆炸物的要求不断变化。基于PICRAMATE的化合物对它们的能量性质以及敏感性差不多。在这项工作中，合成了13种不同的野兔酸盐作为潜在的能量材料，在简单的一步反应中具有高热稳定性，并与商业上使用的铅皮酸盐相比。通过E.?g广泛表征所得化合物。 XRD，IR，EA，DTA和TGA。另外，用BAM落锤和BAM摩擦测试仪测定抗冲击和摩擦的敏感性。此外，探索了静电放电敏感性。使用当前版本的Explo5代码进行所选化合物的能量性能的计算。因此，计算地层的形成，并将X射线密度转化为室温。一些合成的盐显示出具有高放热分解温度的有希望的特性。特别是，无水铷，铯和钡盐 5 </ b> 那 6 </ b> 和 10 </ b> 对于未来的应用，近300℃的分解温度可能是有希望的候选人。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2020年第6期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wurzenberger Maximilian H. H.&option=202" target="_blank" rel="nofollow">Wurzenberger Maximilian H. H.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lechner Jasmin T.&option=202" target="_blank" rel="nofollow">Lechner Jasmin T.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lommel Marcus&option=202" target="_blank" rel="nofollow">Lommel Marcus;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Klap?tke Thomas M.&option=202" target="_blank" rel="nofollow">Klap?tke Thomas M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Stierstorfer J?rg&option=202" target="_blank" rel="nofollow">Stierstorfer J?rg;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryLudwig-Maximilian University of MunichButenandtstr. 5–13 81377 Munich Germany;</p> <p>Department of ChemistryLudwig-Maximilian University of MunichButenandtstr. 5–13 81377 Munich Germany;</p> <p>Department of ChemistryLudwig-Maximilian University of MunichButenandtstr. 5–13 81377 Munich Germany;</p> <p>Department of ChemistryLudwig-Maximilian University of MunichButenandtstr. 5–13 81377 Munich Germany;</p> <p>Department of ChemistryLudwig-Maximilian University of MunichButenandtstr. 5–13 81377 Munich Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Picramic Acid&option=203" rel="nofollow">Picramic Acid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Energetic Materials&option=203" rel="nofollow">Energetic Materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Energetic Salts&option=203" rel="nofollow">Energetic Salts;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thermally Stable Explosives&option=203" rel="nofollow">Thermally Stable Explosives;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nitroaromatic Compounds&option=203" rel="nofollow">Nitroaromatic Compounds;</a> </p> <div class="translation"> 机译：野生酸;能量材料;能量盐;热稳定的炸药;硝基芳族化合物; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024626230.html">Salts of Picramic Acid – Nearly Forgotten Temperature‐Resistant Energetic Materials</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wurzenberger Maximilian H. 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