Paired carbonate-organic carbon and nitrogen isotope variations in Lower Mississippian strata of the southern Great Basin, western United States

摘要

AbstractThe Early Mississippian K-O (Kinderhookian-Osagean) carbon isotope (δ13C) excursion or TICE (mid-Tournaisian carbon isotope excursion) is one of the most prominent positive δ13C excursions of the Phanerozoic. Recent studies raise uncertainties about the representative shape (single vs. double spikes) and magnitude of this δ13C excursion (3‰ to ≥6‰ in South China; ≥5.5‰ in Europe; and ≥7‰ in North America) and the 3‰ unidirectional increase in nitrogen isotopes across the δ13C excursion, which is unanticipated considering the amount of organic carbon burial required to form the δ13C excursion and the resultant oxygen increase and global cooling. To test if stratigraphic completeness and spatial isotope variations caused such uncertainties, we have conducted paired carbonate carbon (δ13Ccarb), organic carbon (δ13Corg) and nitrogen (δ15N) isotope analyses across the K-O interval in two well-exposed sections of the southern Great Basin, western United States. The two sections represent proximal shallow-water and distal deep-water depositional settings of a west-dipping carbonate ramp. In the distal ramp section where no exposure surface is present, both δ13Ccarband δ13Corgshow double spikes with peak δ13Ccarbvalues up to 7‰