Improved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold‐speckled Silica Nanoparticles

Dube Edith; Oluwole David O.; Nyokong Tebello

摘要

Abstract > This work reports on the synthesis of tetrakis‐[(thiophineethoxy) phthalocyaninato] indium( <fc>II</fc> ) chloride (3). The photophysical behavior of complex 3 was compared to that of the Zn derivative (tetrakis‐[(thiophineethoxy) phthalocyaninato] zinc( <fc>II</fc> ) (complex 2)). The compounds were interacted with gold‐speckled silica ( <fc>GSS</fc> ) nanoparticles via Au–S self assembly to afford the conjugates (2– <fc>GSS</fc> and 3– <fc>GSS</fc> ). The photophysicochemical behavior of the compounds and their conjugates were assessed. The conjugates afforded a decrease in fluorescence quantum yields and lifetimes with improved triplet and singlet oxygen quantum yields in comparison with complexes 2 and 3 alone. The complexes and their conjugates could serve as good candidates for photodynamic therapy. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract xmlns =“http://www.wiley.com/namespaces/wiley”type =“main”xml：id =“php12879-abs-abs-0001”xml：lang =“en”> <title type =“main” >摘要</ title> >关于四苯甲酸盐 - [（硫氰基乙氧基）酞菁]氯化铟（3）的合成的工作报告。将复合物3的光学性行为与Zn衍生物（四 - [（硫氰基乙氧基）酞菁]锌（复合物2））进行比较。通过AU-S自组装将该化合物与金斑点二氧化硅（<Fc> GSS </ Fc>）纳米颗粒相互作用，得到缀合物（2- <Fc> GSS </ Fc>和3- <Fc> GSS </ FC>）。评估化合物及其缀合物的光药性化学性能。缀合物提供荧光量子产率和寿命的降低，与单独的复合物2和3相比，具有改善的三重态和单态氧量子产率。复合物及其共轭可以作为光动力治疗的良好候选者。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29317/'>《Photochemistry and Photobiology: An International Journal》</a> <b style="margin: 0 2px;">|</b><span>2018年第3期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dube Edith&option=202" target="_blank" rel="nofollow">Dube Edith;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Oluwole David O.&option=202" target="_blank" rel="nofollow">Oluwole David O.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nyokong Tebello&option=202" target="_blank" rel="nofollow">Nyokong Tebello;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryRhodes UniversityGrahamstown South Africa;</p> <p>Department of ChemistryRhodes UniversityGrahamstown South Africa;</p> <p>Department of ChemistryRhodes UniversityGrahamstown South Africa;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4815.html" title="光化学、辐射化学、超声波作用的化学过程">光化学、辐射化学、超声波作用的化学过程;</a><a href="https://www.zhangqiaokeyan.com/clc/1345.html" title="生物光学">生物光学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> </p> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024468269.html">Improved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold‐speckled Silica Nanoparticles</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dube Edith&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dube Edith,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Oluwole David O.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Oluwole David O.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nyokong Tebello&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nyokong Tebello </a> <a href="/journal-foreign-29317/" target="_blank" rel="nofollow" class="tuijian_authcolor">Photochemistry and Photobiology: An International Journal .</a> <span>2018</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：硫代乙氧基取代金属酞菁对金斑硅胶纳米粒子固定化的显微听力和光化学特性</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020301714.html">Synthesis of tetra-substituted metallophthalocyanines: Spectral, structural, computational studies and investigation of their photophysical and photochemical properties</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guzel Emre&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guzel Emre,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gunsel Armagan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gunsel Armagan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tuzun Burak&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tuzun Burak,</a> <a href="/journal-foreign-29564/" target="_blank" rel="nofollow" class="tuijian_authcolor">Polyhedron: The International Journal for Inorganic and Organometallic Chemistry .</a> <span>2019</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：四取代金属酞菁的合成：光谱，结构，计算研究及其光学和光化学特性的研究</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704013257513.html">Diphenylethoxy-substituted metal-free and metallophthalocyanines as potential photosensitizer for photodynamic therapy: synthesis and photophysical and photochemical properties</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yilmaz Yusuf&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yilmaz Yusuf,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Erdogmus Ali&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Erdogmus Ali,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sener Muhammet Kasim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sener Muhammet Kasim </a> <a href="/journal-foreign-33079/" target="_blank" rel="nofollow" class="tuijian_authcolor">Turkish journal of chemistry .</a> <span>2014</span><span>,第6期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二苯基乙氧基取代的无金属和金属酞菁类化合物作为光动力疗法的潜在光敏剂：合成以及光物理和光化学性质</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-286097_thesis/0705014381920.html">Palladium complex of octaphenyl-substituted pyrazinoporphyrazine: synthesis, photochemical and photophysical properties</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=A D Kosov&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">A D Kosov,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=T V Dubinina&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">T V Dubinina,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=A N Volov&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">A N Volov </a> <a href="/conference-foreign-286097/" target="_blank" rel="nofollow" class="tuijian_authcolor">Interdisciplinary Scientific Forum with International Participation on New Materials and Promising Technologies .</a> <span>2019</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：辛烷基取代的吡嗪卟啉卟喔嗪的钯络合物：合成，光化学和光药性</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061147326.html">Photochemical and photophysical properties of gold(I) complexes and phosphorescence sensitization of organic luminophores.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=El-Bjeirami, Oussama.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">El-Bjeirami, Oussama. </a> <span>2006</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：金（I）配合物的光化学和光物理性质以及有机发光体的磷光敏化。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040003401770.html">Photochemical and photophysical properties of carotenoid immobilized on a surfactant micellar medium including chlorophyll as an artificial photosynthesis system</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yoshiko Fuchino&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yoshiko Fuchino,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yutaka Amao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yutaka Amao </a> <span>2006</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固定在包括叶绿素的表面活性剂胶束介质上的类胡萝卜素的光化学和光物理性质作为人工光合作用系统</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100089126151.html">Photophysical and photochemical behaviour of metallophthalocyanines effect of nanoparticles and molecules of biological importance</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Idowu Mopelola Abidemi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Idowu Mopelola Abidemi </a> <span>2009</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：金属酞菁的光物理和光化学行为对纳米粒子和分子具有生物学重要性</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_imaging-science-photochemistry_thesis/0201231999148.html">N-丁基-2-乙氧基硫代吖啶酮的光化学反应机理</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李晓娜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李晓娜</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张育川&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张育川</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张默君&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张默君</a> <span> <a href="/journal-cn-10992/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 影像科学与光化学 </a> </span> <span> . 2002</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-changchun-university-science-technology-natural-edition_thesis/0201247958278.html">烷氧基取代金属酞菁的合成及其光谱特性的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=强娜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 强娜</a> <span> <a href="/journal-cn-4512/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 长春理工大学学报（自然科学版） </a> </span> <span> . 2007</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-tianjin-university-science-technology_thesis/0201250795265.html">烷氧基取代金属酞菁的合成及其光谱特性研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱倩女&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱倩女</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李树材&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李树材</a> <span> <a href="/journal-cn-4722/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 天津科技大学学报 </a> </span> <span> . 2002</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_infrared-technology_thesis/0201236104637.html">无取代硫代双烯金属络合物的合成及其在夜视兼容技术中应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=门金凤&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 门金凤</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=程海峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,程海峰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈朝辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈朝辉</a> <span> <a href="/journal-cn-8747/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 红外技术 </a> </span> <span> . 2007</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-chimica-sinica_thesis/0201294062433.html">1,2,4-三嗪类化合物的研究——XXI.3-甲硫基-5-氧代-2,5-二氢-1,2,4-三嗪的取代苯磺酰化反应及6-碳的亲电特性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韩梅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 韩梅</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=施栩翎&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,施栩翎</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨振军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨振军</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 1994</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311616020.html">咖啡渣活性炭的制备及其对丁基二硫代碳酸钾和重金属镍的吸附特性研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=庄圣炜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 庄圣炜</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203837001.html">一种单核氟取代双金属酞菁配合物/活性炭锂亚硫酰氯电池催化材料及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN109830699B </span> <span> . 2020.07.14</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120100778930.html">一种单核氟取代双金属酞菁配合物/活性炭锂亚硫酰氯电池催化材料及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN109830699A </span> <span> . 2019-05-31</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130427009447.html">METHOD FOR MANUFACTURING PATTERNED GOLD NANOPARTICLE FILMS, CAPABLE OF OBTAINING EXCELLENT ELECTRICAL PROPERTIES AND OPTICAL PROPERTIES USING ELECTRON IRRADIATION AND POST-PYROLYSIS, THE GOLD NANOPARTICLE FILMS PREPARED BY THE SAME, AND A BIOCHEMICAL SENSOR INCLUDING THE GOLD NANOPARTICLE FILMS</a> <b>[P]</b> . <span> 外国专利：  KR20100084372A </span> <span> . 2010-07-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制造图案化的金纳米粒子膜的方法，该方法可利用电子辐照和热解后获得优异的电学性质和光学性质，由其制备的金纳米粒子膜以及包含金的生物化学传感器 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130421599970.html">METHOD OF CAPTURING VIRUS BY SULFATED SUGAR CHAIN IMMOBILIZED GOLD NANOPARTICLE AND DEXTRAN SULFATE IMMOBILIZED GOLD NANOPARTICLE, FRACTIONATING METHOD, IMMUNIZING METHOD, AND METHOD OF PRODUCING ANTIVIRAL ANTIBODY</a> <b>[P]</b> . <span> 外国专利：  JP2013159567A </span> <span> . 2013-08-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：硫糖链固定化金纳米粒子和右旋硫酸盐固定化金纳米粒子捕获病毒的方法，分馏法，免疫方法和生产抗病毒抗体的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130412028610.html">Method for producing gold nanoparticles hollow inside, protected by nanometric silica film, the hollow inside gold nanoparticles coated with nanometric silica film and their application as nanoresonators</a> <b>[P]</b> . <span> 外国专利：  PL409821A1 </span> <span> . 2016-04-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：纳米二氧化硅膜保护的空心内部金纳米颗粒的制备方法，纳米二氧化硅膜包覆的空心内部金纳米颗粒及其在纳米谐振器中的应用 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704024468269','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704024468269down" data-source="7," data-out-id="BJOM9YtslY/5a0J7/zznUA==," data-f-source-id="7" data-title="Improved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold‐speckled Silica Nanoparticles" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="29317" id="journalid"> <input type="hidden" value="4" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Improved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold‐speckled Silica Nanoparticles"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> function kefu(customization) { var from = GetQueryString("from"); if (from == null || from == "") { from = "other"; } var url = getWxWorkQrCode(55, from, customization); if (url == "" || typeof url == 'undefined') { url = "https://wework.qpic.cn/wwpic/994838_0LUTS-VqR0quT1N_1675665967/0"; } tipDocGuidance(url, '人工辅助获取外文期刊材料'); } $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>