Controlling Cu-Sn mixing so as to enable higher critical current densities in RRP (R) Nb3Sn wires

摘要

Dipole magnets for the proposed Future Circular Collider (FCC) demand specifications significantly beyond the limits of all existing Nb3Sn wires, in particular a critical current density (J(c)) of more than 1500 A mm(-2) at 16 T and 4.2 K with an effective filament diameter (D-eff) of less than 20 mu m. The restacked-rod-process (RRP (R)) is the technology closest to meeting these demands, with a J(c) (16 T) of up to 1400 A mm-2, residual resistivity ratio 100, for a sub element size D-s of 58 mu m (which in RRP (R) wires is essentially the same as D-eff). An important present limitation of RRP (R) is that reducing the sub-element size degrades J(c) to as low as 900 A mm(-2) at 16 T for D-s = 35 mu m. To gain an understanding of the sources of this J(c) degradation, we have made a detailed study of the phase evolution during the Cu-Sn 'mixing' stages of the wire heat treatment that occur prior to Nb3Sn formation. Using extensive microstructural quantification, we have identified the critical role that the Sn-Nb-Cu ternary phase (Nausite) can play. The Nausite forms as a well-defined ring between the Sn source and the Cu/Nb filament pack, and acts as an osmotic membrane in the 300 degrees C-400 degrees C range - greatly inhibiting Sn diffusion into the Cu/Nb filament pack while supporting a strong Cu counter-diffusion from the filament pack into the Sn core. This converts the Sn core into a mixture of the low melting point (408 degrees C) eta phase (Cu6Sn5) and the more desirable epsilon phase (Cu3Sn), which decomposes at 676 degrees C. After the mixing stages, when heated above 408 degrees C towards the Nb3Sn reaction, any residual eta liquefies to form additional irregular Nausite on the inside of the membrane. All Nausite decomposes into NbSn2 on further heating, and ultimately transforms into coarse-grain (and often disconnected) Nb3Sn which has little contribution to current transport. Understanding this critical Nausite reaction pathway has allowed us to s