Controlled synthesis of the antiperovskite oxide superconductor Sr3-xSnO

摘要

A large variety of perovskite oxide superconductors are known, including some of the most prominent high-temperature and unconventional superconductors. However, superconductivity among the oxidation state inverted material class, the antiperovskite oxides, was recently reported for the first time. In this superconductor, Sr3-xSnO, the unconventional ionic state Sn4- is realized and possible unconventional superconductivity due to a band inversion has been discussed. Here, we discuss an improved facile synthesis method, making it possible to control the strontium deficiency in Sr3-xSnO. Additionally, a synthesis method above the melting point of Sr3SnO is presented. We show temperature dependence of magnetization and electrical resistivity for superconducting strontium deficient Sr3-xSnO (T-c similar to 5K) and for Sr3SnO without a superconducting transition in alternating current susceptibility down to 0.15 K. Further, we reveal a significant effect of strontium raw material purity on the superconductivity and achieve substantially increased M/M-Meissner (similar to 1) compared to the highest value reported so far. More detailed characterizations utilizing powder x-ray diffraction and energy-dispersive x-ray spectroscopy show that a minor cubic phase, previously suggested to be another Sr3-xSnO phase with a slightly larger lattice parameter, is SrO. The improved characterization and controlled synthesis reported herein enable detailed investigations on the superconducting nature and its dependency on the strontium deficiency in Sr3-xSnO.