Charge-transfer kinetics and cyclic properties of inorganic all-solid-state electrochromic device with remarkably improved optical memory

摘要

AbstractOptical memory effect plays a critical role in energy-saving coefficient of electrochromic devices (ECDs). Due to the finite electron-blocking capacity of ions electrolyte layer and the weak interfacial energy between the ions electrolyte layer and electrochromic layers, typically five-layer inorganic all-solid-state ECDs generally suffer from poor optical memory. A seven-layer inorganic ECD with significantly improved optical memory is designed by means of the embedment of Ta2O5layers between ions conductive layer and electrochromic layers. Compared with the typical five-layer ECD-1 (ITO/NiOx/LiNbO3/WO3/ITO), the seven-layer ECD-2 with the structure of ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO presents much less leakage current, larger optical modulation and higher coloration efficiency during electrochemical cycling. The further analyses reveal that the embedded Ta2O5layers greatly increase the energy barrier between NiOx, WO3and LiNbO3, imposing restrictions on the transfer kinetics of electrons contributing to the leakage current and enlarging the threshold potential available to ECD-2, which gives rise to a high coloration efficiency up to 98.0cm