Cobalt Phosphide Coupled with Heteroatom‐Doped Nanocarbon Hybrid Electroctalysts for Efficient, Long‐Life Rechargeable Zinc–Air Batteries

Ahn Sung Hoon; Manthiram Arumugam

摘要

Abstract >Metal phosphides and heteroatom‐doped carbons have been regarded as promising candidates as bifunctional catalysts for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). However, both have suffered from stability issues during repeated ORR and OER operations in zinc–air batteries (ZABs). Herein, this study reports a versatile cobalt‐based hybrid catalyst with a 1D structure by integrating the metal‐organic framework‐derived conversion approach and an in situ crosslinking method. Among them, the 1D hybrid catalyst composed of ultrasmall cobalt phosphide nanoparticles supported by nitrogen‐, sulfur‐, phosphorus‐doped carbon matrix shows remarkable bifunctional activity close to that of the benchmark precious‐metal catalysts along with an excellent durability in the full potential range covering both the OER and ORR. The overall overpotential of the rechargeable ZABs can be greatly reduced with this bifunctional hybrid catalyst as an air‐electrode, and the cycling stability outperforms the commercial Pt/C catalyst. It is revealed that the cobalt phosphide nanoparticles are in situ converted to cobalt oxide under the accelerated conditions during OER (and/or ORR) of the ZABs and reduces the anodic current applied to the carbon. This contributes to the stability of the carbon material and in maintaining the high initial catalytic properties of the hybrid catalyst. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >金属磷化物杂原子掺杂的碳被认为是有希望的候选者作为用于氧进化反应（oer）和氧还原反应（ORR）的双官能催化剂。然而，两者都在锌 - 空气电池（ZABs）中的重复ORR和OER操作期间遭受了稳定性问题。这里，本研究通过整合金属 - 有机框架推导的转化方法和原位交联方法向基于钴基的杂化催化剂与1D结构报告。其中，由氮 - ，硫 - 磷掺杂碳基质支持的超大钴磷化物纳米粒子组成的1D杂化催化剂显示出靠近基准贵金属催化剂的显着双官能活性，以及在全潜在范围内具有出色的耐用性覆盖OER和ORR。通过作为空气电极的双官能杂合催化剂，可以大大降低可充电Zab的整体过电位，并且循环稳定性优于商业Pt / C催化剂。揭示碳化钴纳米粒子原位在Zab的oer（和/或Orr）期间在加速条件下转化为氧化钴，并减少施加到碳的阳极电流。这有助于碳材料的稳定性和保持杂交催化剂的高初始催化性能。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-28247/'>《Small》</a> <b style="margin: 0 2px;">|</b><span>2017年第40期</span><b style="margin: 0 2px;">|</b><span>共1页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ahn Sung Hoon&option=202" target="_blank" rel="nofollow">Ahn Sung Hoon;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Manthiram Arumugam&option=202" target="_blank" rel="nofollow">Manthiram Arumugam;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Materials Science and Engineering Program and Texas Materials InstituteThe University of Texas at AustinAustin TX 78712 USA;</p> <p>Materials Science and Engineering Program and Texas Materials InstituteThe University of Texas at AustinAustin TX 78712 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bifunctional catalyst&option=203" rel="nofollow">bifunctional catalyst;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cobalt phosphide&option=203" rel="nofollow">cobalt phosphide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=heteroatom‐doped carbon&option=203" rel="nofollow">heteroatom‐doped carbon;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal‐organic framework&option=203" rel="nofollow">metal‐organic framework;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=zinc–air batteries&option=203" rel="nofollow">zinc–air batteries;</a> </p> <div class="translation"> 机译：双官能催化剂;钴磷化钴;杂原子掺杂的碳;金属 - 有机框架;锌 - 空气电池; 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