Costerfield antimony-gold deposit, southeast Australia: Coupling between brittle deformation and dissolution-precipitation reactions in the Melbourne Zone

摘要

Graphical abstractDisplay OmittedHighlights?Emplacement of antimony-gold lodes related to faulting events.?Seismic reflection data and crustal faults.?Neutron diffraction data supporting dissolution-precipitation creep.?3D neutron tomography showing gold distributions.?Source of Sb-Au tied to structural and stratigraphic controls.AbstractThe antimony-gold deposits at Costerfield are a swarm of ‘dyke-like’ antimony-gold lodes within a brittle transpressional fault system. They are hosted in the Lower Silurian sedimentary rocks of the Melbourne Zone of the Lachlan Orogen. Individual lodes are dominated by stibnite or stibnite-gold and widths vary from 1cm to ～200cm (averaging 30cm) and lengths can exceed 1km. Lodes occur as fault-parallel layers or lenses mantled by deformed quartz-rich margins or overgrowths of hydrothermal quartz and carbonate. Inclusions in the stibnite-rich lodes include vuggy randomly oriented prismatic crystals, crack-sealed and stretched quartz with sugary mosaics of equant quartz grains and quartz breccias. Randomly oriented quartz and stibnite textures, common in the centre of the lodes, indicate free growth from a fluid. Throughout the mineralized system, the hydrothermal stibnite has replaced and overgrown the earlier quartz. Deformed lode margins preserve sub-horizontal lineations and evidence of oblique crack-seal re-opening that reflect emplacement associated with late sinistral strike-slip movements in bounding faults. Crystallographic orientation data collected from the marginal quartz, using neutron diffraction and supported by microstructural observations, reveal that lode emplacement also involved dissolution-precipitation creep and pressure solution. Both the marginal quartz and the lodes are overprinted by later microfractures, within which there has been precipitation of stibnite, pyrite, arsenopyrite, sphalerite and minor gold. 3D neutron tomography revealed individual gold crystals, with gold voxel sizes ranging from 140μm to ～580μm, were located in late arsenopyrite-gold domains that overprint the stibnite. The mechanical evolution of the lodes involved short-lived brittle processes in combination with dissolution-precipitation crystallization in active fault zones. These ore bodies provide insights about the dynamics of fluid flow and flow velocities when faults breach over-pressured reservoirs of hydrothermal fluid. Our results also suggest that the Costerfield deposit was formed directly from metal-rich metamorphic fluids prod