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首页> 外文期刊>Russian journal of physical chemistry, B. >Initiator Based on the Cu(II) and Cetyl Trimethyl Ammonium Bromide Compounds that Generates Free Radicals in the Decomposition of tert-Butyl Hydroperoxide in Optimum Temperature Conditions
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Initiator Based on the Cu(II) and Cetyl Trimethyl Ammonium Bromide Compounds that Generates Free Radicals in the Decomposition of tert-Butyl Hydroperoxide in Optimum Temperature Conditions

机译:基于Cu(II)和十六烷基铵溴化物的引发剂,其在最佳温度条件下在叔丁基氢过氧化氢的分解中产生自由基

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摘要

The two-component composition consisting of complex copper Cu(II) compounds and cationic surface-activated substance cetyl trimethyl ammonium bromide (CTAB) exhibits high catalytic reactivity during decomposition of tert-butyl hydroperoxide. One specific characteristic of the effects of the Cu(II) + CTAB binary system consists in its high rate of processing without visible signs of deactivation in the transformation of significant amounts of the reagent in optimum temperature conditions.
机译:由复合铜Cu(II)化合物和阳离子表面活化物质十六烷基溴化物(CTAB)组成的双组分组合物在分解叔丁基氧化氧化酯的分解期间表现出高催化反应性。 Cu(II)+ CTAB二元体系的效果的一种特异性特征在于在最佳温度条件下在大量试剂的转化中停用的可见性加工速率。

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