Unexpected Carbon-Selenium Bond Formation in the Reaction of Secondary Phosphine Selenides with Benzoylphenylacetylene

Volkov P. A.; Telezhkin A. A.; Khrapova K. O.; Ivanova N. I.; Albanov A. I.; Apartsin K. A.; Gusarova N. K.; Trofimov B. A.

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Unexpected Carbon-Selenium Bond Formation in the Reaction of Secondary Phosphine Selenides with Benzoylphenylacetylene

机译：用苯甲酰苯苯乙烯二次磷酸硒化物反应中意外的碳 - 硒键形成

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Secondary phosphine selenides reacted as selenating agents with benzoylphenylacetylene in wet acetonitrile (70-72A degrees C) to give bis(2-benzoyl-1-phenylvinyl) selenide in up to 43% yield.

机译：仲膦酸酯在湿乙腈（70-72A℃）中用苯甲酰苯苯乙烯（70-72A℃）反应，得到双（2-苯甲酰基-1-苯基乙烯基）硒化烷基，高达43％的产率。

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来源
《Russian Journal of General Chemistry》 |2017年第12期|共2页
作者
Volkov P. A.; Telezhkin A. A.; Khrapova K. O.; Ivanova N. I.; Albanov A. I.; Apartsin K. A.; Gusarova N. K.; Trofimov B. A.;
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作者单位

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

Irkutsk Sci Ctr Surg &

Traumatol Ul Bortsov Revolyutsii 1 Irkutsk 664003 Russia;

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

Russian Acad Sci Favorskii Irkutsk Inst Chem Siberian Branch Ul Favorskogo 1 Irkutsk 664033 Russia;

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正文语种 eng
中图分类化学;
关键词
secondary phosphine selenides; benzoylphenylacetylene; bis(2-benzoyl-1-phenylvinyl) selenide;

机译：二次磷酸硒化物;苯甲酰苯乙烯;双（2-苯甲酰-1-苯基乙烯基）硒化酰胺;

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1. Unexpected Carbon-Selenium Bond Formation in the Reaction of Secondary Phosphine Selenides with Benzoylphenylacetylene [J] . Volkov P. A., Telezhkin A. A., Khrapova K. O., Russian Journal of General Chemistry . 2017,第12期

机译：用苯甲酰苯苯乙烯二次磷酸硒化物反应中意外的碳 - 硒键形成
2. Reaction of Secondary Phosphine Selenides with Elemental Selenium:Synthesis of Bis(diorganoselenophosphoryl)selenides [J] . A. V. Artemev, N. K. Gusarova, S. F. Malysheva Russian Journal of General Chemistry . 2010,第10期

机译：次膦硒化物与元素硒的反应：双（二有机硒代磷酰基）硒化物的合成
3. Catalytic (Ni, Pd, Pt, Rh and Au) and Non-Catalytic Reactions for Atom-Economic Carbon-Sulfur, Carbon-Selenium and Carbon-Tellurium Bonds Formation [J] . Valentine P. Ananikov, Sergey S. Zalesskiy, Irina P. Beletskaya Current Organic Synthesis . 2011,第1期

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4. Reaction of α-Imino Thioesters and the Subsequent C-C Bond Formation with the Unexpected Alkylthio Rearrangement [C] . Isao Mizota, Makoto Shimizu 日本化学会春季年会講演予稿集 . 2018

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5. Part I. Palladium-catalyzed alkenylation and alkynylation of nucleosides in aqueous media. Part II. Palladium-catalyzed carbon-selenium bond formation for unsymmetrical diaryl selenides. [D] . Cho, Joon Hyung. 2007

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6. A Single Phosphine Ligand Allows for the Palladium-Catalyzed Intermolecular C–O Bond Formation with Secondary and Primary Alcohols [O] . Xiaoxing Wu, Brett P. Fors, Stephen L. Buchwald -1

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7. Ruthenium(ii) complexes containing a phosphine-functionalized thiosemicarbazone ligand: synthesis, structures and catalytic C–N bond formation reactions via N-alkylation [O] . Rangasamy Ramachandran, Govindan Prakash, Sellappan Selvamurugan, 2015

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Unexpected Carbon-Selenium Bond Formation in the Reaction of Secondary Phosphine Selenides with Benzoylphenylacetylene

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