Motukoreaite from the Klodawa Salt Dome, Central Poland

摘要

Motukoreaite, Mg6Al3(OH)(18)[Na(H2O)(6)][SO4](2)center dot 6H(2)O, is a poorly-known, rare layered double hydroxide mineral belonging to the wermlandite group in the hydrotalcite supergroup. It was found in abundant quantities (at least hundreds of thousands of Mt) in the roof part the Younger Potash unit of the Leine cyclothem on the Klodawa Salt Dome in central Poland (Permian-Mesozoic basin of Central Europe), outside its known typical environments like altered basalts and basaltic tuffs, including those deposited in submarine volcanic areas. The mineral displays varying SO42-, Na+ and H2O contents with negligible CO32-, corresponding to the mean composition Mg-5.75(Al3.20Fe0.043+)(Sigma 3.25)(OH)(18.00){[Na(H2O)(6)](0.72)square(0.28)} [(SO4)(1.67)(CO3)(0.03)(OH)(0.57)]center dot 0.72H(2)O. It can be related to the partly dehydrated, hypothetical end-member Mg6Al3(OH)(18)[Na(H2O)(6)][(SO4)(2)]center dot 6H(2)O. The Klodawa motukoreaite represents the hexagonal, 3-layer polytype with the 3 x 3 superstructure in the xy plane, and unit cell a = b = 9.191(2)-9.199(2) angstrom, i.e. = 3 x 3.064-3.066 angstrom and c = 33.529(9)-33.562(7) angstrom, i.e. = 3 x 11.174-11.187 angstrom. The mineral was formed by alteration of clays delivered to the basin by an aeolian overprint and co-sedimented along with the evaporite sequence, initiated under the influence of Mg2+- and SO42--bearing brines at temperatures not exceeding 160 - 200 degrees C, released from the evaporites during diagenetic/metamorphic processes.