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Core-sheath fiber-polyurethane guided solid particles grafted on polyacrylonitrile fiber surface and its application in adsorbing acetone

机译:芯鞘纤维 - 聚氨酯引导固体颗粒接枝在聚丙烯腈纤维表面上及其在吸附丙酮中的应用

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This manuscript will provide the successful application of polyurethane-guided solid particles to core-sheath electrospun fibers prepared on the surface of polyacrylonitrile fibers and their application in removing acetone from indoor air pollution. The difference between single-fluid electrospinning and coaxial electrospinning was compared using a coaxial electrospinning process. Through the transmission electron microscope image, the polyurethane-bonded non-spun solid MCM-41 can be well wrapped on the outside of the polyacrylonitrile fiber. By using the functional groups in MCM-41 and PU and the high specific surface area of the fibers, it is used to treat low concentrations of acetone in the chamber. The adsorption results showed that acetone with an initial concentration of 10 ppm achieved effective adsorption using PU@10MCM/PAN, and the maximum adsorption amount was 10.32 mu g/g. The Langmuir and Freundlich model can be used to describe the p88rocess. The Experimental value is in good agreement with the Langmuir model. The desorption results show that the adsorption capacity can be even after 5 cycles of reuse. The mechanism of preparation and application of polyurethane/polyacrylonitrile core-sheath electrospun fibers was proposed. This work shows that our new structure of fiber provides a theoretical basis for the adsorption system of air purifiers, effectively preventing the harmful organic gases from invading the human body.
机译:该原稿将在制备在聚丙烯腈纤维表面上制备的核心鞘静电纤维和它们在从室内空气污染中除去丙酮中制备的芯鞘静电纤维的成功应用。使用同轴电纺丝工艺比较单流体静电纺丝和同轴电纺丝之间的差异。通过透射电子显微镜图像,聚氨酯键合的非旋转固体MCM-41可以很好地缠绕在聚丙烯腈纤维的外部。通过使用MCM-41和PU中的官能团和纤维的高比表面积,用于在腔室中处理低浓度的丙酮。吸附结果表明,使用PU @ 10MCM /锅初始浓度为10ppm的丙酮,最大吸附量为10.32μg/ g。 Langmuir和Freundlich模型可用于描述p88rocess。实验价值与Langmuir模型吻合良好。解吸结果表明吸附容量甚至可以在5个循环重用后。提出了聚氨酯/聚丙烯腈芯鞘鞘纤维纤维的制备和施加的机理。这项工作表明,我们的新纤维结构为空气净化器的吸附系统提供了理论依据,有效地防止了侵入人体的有害有机气体。

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