A novel bio‐based phthalonitrile resin derived from catechin: synthesis and comparison of curing behavior with petroleum‐based counterpart

Qi Yu; Weng Zhihuan; Wang Jinyan; Zhang Shouhai; Zong Lishuai; Liu Cheng; Jian Xigao

摘要

Abstract >The development of bio‐based thermosetting resins with good thermal stability can potentially afford sustainable polymers as replacements for petroleum‐based polymers. We report a practical route to a novel catechin‐based phthalonitrile resin precursor (CA‐Ph), which contains free phenolic hydroxyl groups that result in ‘self‐curing’ at elevated temperatures to afford a thermostable polymer. Comparison of the performance of this CA‐Ph resin with that of a conventional petroleum‐based bisphenol A phthalonitrile resin (BPA‐Ph; containing 5?wt% of the curing agent 4,4′‐diaminodiphenylsulfone) revealed that CA‐Ph exhibits a lower melting point and curing temperature. Cured CA‐Ph resin retains 95% of its weight at 520?°C under a nitrogen atmosphere, which compares favorably with results obtained for BPA‐Ph resin that retains 95% of its weight at a lower temperature of 484?°C. Kinetic results indicated that the curing reactions of both CA‐Ph and BPA‐Ph systems follow an autocatalytic mechanism. These results suggest that catechin is a useful bio‐based feedstock for the preparation of self‐curing and thermally stable phthalonitrile resins for advanced technological applications. ? 2017 Society of Chemical Industry </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >具有良好的热稳定性的生物基热固性树脂的研制可能是可持续的聚合物作为石油基聚合物的替代品。我们报告了新型儿茶素的酞酮腈树脂前体（Ca-pH）的实际途径，其含有游离酚羟基，其在升高的温度下产生“自固化”，得到热稳定聚合物。将该Ca-pH基于磷酸酞酮树脂（BPA-pH值4,4'-二氨基二苯基砜的普邻苯二甲醇的性能与常规石油基双酚的性能进行比较显示CA-pH表现出CA-pH较低的熔点和固化温度。固化的Ca-pH树脂在氮气氛下在520℃下保持95％的重量，这与用于BPA-pH树脂的结果相比，其在484℃的较低温度下保持95％的重量。动力学结果表明，Ca-pH和BPA-pH系统的固化反应遵循自催化机制。这些结果表明，儿茶素是一种用于制备用于先进技术应用的自固化和热稳定的酞酮腈树脂的有用生物基原料。还2017年化学工业学会</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24639/'>《Fortschritte der Physik 》</a> <b style="margin: 0 2px;">|</b><span>2018年第3期</span><b style="margin: 0 2px;">|</b> <span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qi Yu&option=202" target="_blank" rel="nofollow">Qi Yu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Weng Zhihuan&option=202" target="_blank" rel="nofollow">Weng Zhihuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Jinyan&option=202" target="_blank" rel="nofollow">Wang Jinyan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Shouhai&option=202" target="_blank" rel="nofollow">Zhang Shouhai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zong Lishuai&option=202" target="_blank" rel="nofollow">Zong Lishuai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Cheng&option=202" target="_blank" rel="nofollow">Liu Cheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jian Xigao&option=202" target="_blank" rel="nofollow">Jian Xigao;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> <p>Liaoning High Performance Resin Engineering Research Center Department of Polymer Science and MaterialsDalian University of TechnologyDalian PR China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/158.html" title="物理学">物理学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bio‐based&option=203" rel="nofollow">bio‐based;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=phthalonitrile resin&option=203" rel="nofollow">phthalonitrile resin;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=self‐curing&option=203" rel="nofollow">self‐curing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catechin&option=203" rel="nofollow">catechin;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thermosetting&option=203" rel="nofollow">thermosetting;</a> </p> <div class="translation"> 机译：基于生物的;酞氯腈树脂;自我固化;儿茶素;热固性; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023606289.html">A novel bio-based phthalonitrile resin derived from catechin: synthesis and comparison of curing behavior with petroleum-based counterpart</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qi Yu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Qi Yu,</a> <a 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Ma,</a> <span>2017</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：离子液体作为一类新型固化剂的邻苯二甲腈树脂的固化行为和性能</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-chimica-sinica_thesis/0201298291350.html">含氟芳杂环化合物的合成 Ⅱ.3,5-二硝基-4-氯三氟甲苯和-3,5-二硝基-2-氯三氟甲苯与含氮亲核试剂的反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吉景顺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 吉景顺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=梁世琴&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,梁世琴</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱贵东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱贵东</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 1989</span><span> ,第4期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-functional-materials_thesis/0201211910319.html">木器用新型不饱和聚酯UV胶衣树脂的合成及其UV-LED下光固化行为研究∗</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈富强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈富强</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄鸿&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄鸿</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=苏嘉辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,苏嘉辉</a> <span> <a href="/journal-cn-7663/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 功能材料 </a> </span> <span> . 2016</span><span> ,第0z1期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201293815584.html">对酞内酰胺基苯甲酰氯衍生试剂合成的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=弓爱君&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 弓爱君</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=叶常明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,叶常明</a> <span> <a href="/journal-cn-56897/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 环境化学 </a> </span> <span> . 1999</span><span> ,第2期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201292314542.html">新型紫外、荧光衍生试剂——对酞内酰胺苯甲酰氯</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郭玉凤&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 郭玉凤</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李景印&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李景印</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李敏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李敏</a> <span> <a href="/journal-cn-57029/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学试剂 </a> </span> <span> . 2002</span><span> ,第3期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-applied-chemistry_thesis/0201272091162.html">对酞内酰胺苯磺酰氯与胺类化合物的衍生反应</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔同&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 崔同</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=傅承光&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,傅承光</a> <span> <a href="/journal-cn-54377/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化学 </a> </span> <span> . 1996</span><span> ,第005期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-60734_thesis/020222786395.html">通过1,1-二氯-2-硝基烯促进羰基化合物与DMF缩合合成取代酚类化合物及其杀虫活性研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Weiwei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Yu Weiwei</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=虞委委&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,虞委委</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Fukai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Wang Fukai</a> <span> <a href="/conference-cn-60734/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化工学会农药专业委员会第十八届年会 </a> <span> <span> . 2018</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314312040.html">新型新烟碱类化合物的合成和杀虫活性测定(三) (Ⅰ)1-(2氯-5-噻唑甲基)-3-甲基-5-酰胺基-1,3,5-六氢三嗪-2-N-硝基亚胺的合成 (Ⅱ)1-呋喃(四氢呋喃)基-5-取代-1,3,5-六氢三嗪-2-N-硝基亚胺的合成和晶体结构</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马旭波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 马旭波</a> <span> . 2011</span> </span> </div> </li> </ul> <ul style="display: 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