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An amino‐based protic ionic liquid as a corrosion inhibitor of mild steel in aqueous chloride solutions

机译：一种基于氨基的质子离子液体作为氯化物溶液水溶液中低碳钢的腐蚀抑制剂

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Abstract > Protic ionic liquids (PILs) have shown to be promising substances as corrosion inhibitors (CIs). In line with this, the aim of this study is to study the performance and propose the corrosion inhibition mechanism of N ‐methyl‐2‐hydroxyethylamine (M‐2HEAOL) and bis‐2‐hidroxyethylamine (B‐HEAOL) oleate, for mild steel, in a neutral chloride solution. Electrochemical characterization was conducted under static and hydrodynamic conditions, and it was revealed that M‐2HEAOL and B‐HEAOL worked as mixed‐type CIs with more interference on the anodic reaction. Inhibition efficiency depended on the concentration reaching 97% of inhibition efficiency in 5?mmol/L concentration. Scanning electron microscopy, optical interferometry, Raman spectroscopy, and Fourier‐transform infrared spectroscopy are used to elicit the chemical composition of the surface film and corrosion morphology of steel in the presence of CIs, the adsorption processes of which involved physical and chemical adsorption between metal and different parts of ionic liquids. The results allowed the proposition of a corrosion inhibition mechanism. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 质子离子液体（Pils）已显示有前途的物质作为腐蚀抑制剂（CIS）。符合这一点，本研究的目的是研究性能并提出腐蚀抑制机制 n </ i> - 在中性氯化物溶液中，甲基-2-羟乙基胺（M-2HEA醇）和双-2-羟乙基甲胺（B-HEAOL）油酸酯，用于温和钢。在静态和流体动力学条件下进行电化学表征，揭示了M-2HEA酚和B-HEAOL作为混合型CIS，具有更多对阳极反应的干扰。抑制效率依赖于浓度达到97％的抑制效率5？mmol / L浓度。扫描电子显微镜，光学干涉测量，拉曼光谱和傅立叶变换红外光谱分辨率在CIS存在下引发钢的表面膜和腐蚀形态的化学成分，其吸附过程涉及金属之间的物理和化学吸附和离子液体的不同部分。结果允许主张腐蚀抑制机制。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24514/'>《Materials and Corrosion》</a> <b style="margin: 0 2px;">|</b><span>2020年第7期</span><b style="margin: 0 2px;">|</b><span>共19页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7194.html" title="金属腐蚀与保护、金属表面处理">金属腐蚀与保护、金属表面处理;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon steel&option=203" rel="nofollow">carbon steel;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=corrosion inhibition&option=203" rel="nofollow">corrosion inhibition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemical techniques&option=203" rel="nofollow">electrochemical techniques;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=protic ionic liquid&option=203" rel="nofollow">protic ionic liquid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=surface analysis&option=203" rel="nofollow">surface analysis;</a> </p> <div class="translation"> 机译：碳钢;腐蚀抑制;电化学技术;质子离子液体;表面分析; 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href="/conference-cn-4042/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2014中国环境科学学会学术年会 </a> <span> <span> . 2014</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316252746.html">水和质子化离子液体水溶液在磷脂双分子层界面处溶剂化行为的分子模拟研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=罗艺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 罗艺</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120711239.html">用于电解氯化氢水溶液或者碱金属氯化物水溶液的方法</a> <b>[P]</b> . <span> 中国专利： CN1849412B </span> <span> . 2011.01.05</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105048533.html">用于电解氯化氢水溶液或者碱金属氯化物水溶液的方法</a> <b>[P]</b> . <span> 中国专利： CN1849412A </span> <span> . 2006-10-18</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130404767661.html">METAL CORROSION INHIBITOR FOR POLYCARBOXYLIC ACID AQUEOUS SOLUTION, METAL CORROSION INHIBITOR AQUEOUS SOLUTION COMPOSITION, AND METAL CORROSION INHIBITING METHOD FOR POLYCARBOXYLIC ACID AQUEOUS SOLUTION</a> <b>[P]</b> . <span> 外国专利：  JP6444105B2 </span> <span> . 2018-12-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：聚羧酸水溶液的金属腐蚀抑制剂，聚羧酸水溶液的金属腐蚀抑制剂和聚羧酸溶液的金属腐蚀抑制方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130413287663.html">METAL CORROSION INHIBITOR FOR POLYCARBOXYLIC ACID AQUEOUS SOLUTION, METAL CORROSION INHIBITOR AQUEOUS SOLUTION COMPOSITION, AND METAL CORROSION INHIBITING METHOD FOR POLYCARBOXYLIC ACID AQUEOUS SOLUTION</a> <b>[P]</b> . <span> 外国专利：  JP2016060932A </span> <span> . 2016-04-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：聚羧酸水溶液的金属腐蚀抑制剂，聚羧酸水溶液的金属腐蚀抑制剂和聚羧酸溶液的金属腐蚀抑制方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130434124083.html">Solution system based on molten ionic liquid e.g. imidazolium salt for dissolving carbohydrate e.g. starch, cellulose or derivative and regeneration e.g. for fiber production also contains water and/or other protic solvent</a> <b>[P]</b> . <span> 外国专利：  DE102005062608A1 </span> <span> . 2007-07-05</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于熔融离子液体的溶液系统用于溶解碳水化合物的咪唑盐，例如淀粉，纤维素或衍生物和再生例如纤维生产中还含有水和/或其他质子溶剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul 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