Electrochemical corrosion behavior of bronze materials in an acid‐containing simulated atmospheric environment

Cai Lankun; Chen Mengjie; Wang Ying; Chen Cheng; Zhang Lehua; Zhou Hao; Wu Laiming; Yan Ying

摘要

Abstract >The present work investigates the corrosion behavior of bronze materials under thin electrolyte layers (TELs) in a simulated atmospheric environment containing formic and acetic acid by electrochemical measurements?as well as surface characterization. The results show that the corrosion of bronze under TEL is significantly faster than that in the bulk solution, and the corrosion rate of bronze is the highest when the thickness of TEL is about 100?μm. Formic acid is observed to be more corrosive than acetic acid. Copper formate and copper acetate hydrate appear in the corrosion products formed on the surface of bronze, suggesting that the organic acid participates in the corrosion process of bronze materials in the simulated atmospheric environment. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XML：lang =“en”type =“main”> <标题类型=“main”>抽象</ title> 本作通过电化学测量，研究了含有甲型和乙酸的模拟大气环境下的薄电解质层（TELS）下青铜材料的腐蚀行为？以及表面表征。结果表明，在电话下的青铜腐蚀明显快于散装溶液中的速度，并且青铜的腐蚀速率是当Tel的厚度约为100Ωμm时的腐蚀速率最高。观察到甲酸比乙酸更腐蚀。铜甲酸盐和醋酸铜水合物出现在青铜表面上形成的腐蚀产物中，表明有机酸参与模拟大气环境中青铜材料的腐蚀过程。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24514/'>《Materials and Corrosion》</a> <b style="margin: 0 2px;">|</b><span>2020年第3期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cai Lankun&option=202" target="_blank" rel="nofollow">Cai Lankun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Mengjie&option=202" target="_blank" rel="nofollow">Chen Mengjie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Ying&option=202" target="_blank" rel="nofollow">Wang Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Cheng&option=202" target="_blank" rel="nofollow">Chen Cheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Lehua&option=202" target="_blank" rel="nofollow">Zhang Lehua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Hao&option=202" target="_blank" rel="nofollow">Zhou Hao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Laiming&option=202" target="_blank" rel="nofollow">Wu Laiming;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Ying&option=202" target="_blank" rel="nofollow">Yan Ying;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process College of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai China;</p> <p>State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process College of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai China;</p> <p>State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process College of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai China;</p> <p>State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process College of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai China;</p> <p>State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process College of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai China;</p> <p>Shanghai MuseumShanghai China;</p> <p>Shanghai MuseumShanghai China;</p> <p>State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process College of Resources and Environmental EngineeringEast China University of Science and TechnologyShanghai China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7194.html" title="金属腐蚀与保护、金属表面处理">金属腐蚀与保护、金属表面处理;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=acetic acid&option=203" rel="nofollow">acetic acid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bronze&option=203" rel="nofollow">bronze;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=corrosion&option=203" rel="nofollow">corrosion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=formic acid&option=203" rel="nofollow">formic acid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thin electrolyte layers&option=203" rel="nofollow">thin electrolyte layers;</a> </p> <div class="translation"> 机译：醋酸;青铜;腐蚀;甲酸;薄电解质层; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" 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