• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Macromolecular chemistry and physics >Structural Behavior of Cylindrical Polystyrene‐ blockblock ‐Poly(ethylene‐butylene)‐ blockblock ‐Polystyrene (SEBS) Triblock Copolymer Containing MWCNTs: On the Influence of Nanoparticle Surface Modification
【24h】

Structural Behavior of Cylindrical Polystyrene‐ blockblock ‐Poly(ethylene‐butylene)‐ blockblock ‐Polystyrene (SEBS) Triblock Copolymer Containing MWCNTs: On the Influence of Nanoparticle Surface Modification

机译：圆柱聚苯乙烯 - block 块-poly（亚乙烯 - 丁烯） - 嵌段嵌段 - 含有mwcnts的三嵌段（Sebbs）三嵌段共聚物：关于纳米颗粒表面改性的影响

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Abstract > In this work, the influence of carbon nanotubes (CNTs) on the self‐assembly of nanocomposite materials made of cylinder‐forming polystyrene‐ block ‐poly(ethylene‐butylene)‐ block ‐polystyrene (SEBS) is studied. CNTs are modified with polystyrene (PS) brushes by surface‐initiated atom transfer radical polymerization to facilitate both their dispersion and the orientation of neighboring PS domains of the block copolymer (BCP) along modified CNT‐PS. Dynamic rheology is utilized to probe the viscoelastic and thermal response of the nanoscopic structure of BCP nanocomposites. The results indicate that nonmodified CNTs increase the BCP microphase separation temperature because of BCP segmental confinement in the existing 3D network formed between CNTs, while the opposite holds for the samples filled with modified CNT‐PS. This is explained by severely retarded segmental motion of the matrix chains due to their preferential interactions with the PS chains of the CNT‐PS. Moreover, transient viscoelastic analysis reveals that modified CNT‐PS have a more pronounced effect on flow‐induced BCP structural orientation with much lower structural recovery rate. It is demonstrated that dynamic‐mechanical thermal analysis can provide valuable insights in understanding the role of CNT incorporation on the microstructure of BCP nanocomposite samples. Accordingly, the presence of CNT has a significant promoting effect on microstructural development, comparable to that of annealing. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract xmlns =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >工作，碳纳米管（CNTs）对由圆柱形聚苯乙烯 - 嵌段嵌段制成的纳米复合材料的自组装的影响 - 聚（乙烯 - 丁烯） - 嵌段 - 研究了聚苯乙烯（SEBS）。通过表面引发的原子转移自由基聚合用聚苯乙烯（PS）刷子改性CNT，以促进它们的分散和嵌段共聚物（BCP）的相邻PS结构域的取向沿改性的CNT-PS。动态流变学用来探测BCP纳米复合材料的纳米镜结构的粘弹性和热响应。结果表明，由于在CNT中形成的现有3D网络中的BCP节段性限制，非副化的CNT增加了BCP播放分离温度，而相对的保持用于填充有修改的CNT-PS的样本。这是由于其优于与CNT-PS的PS链的优先相互作用的主要相互作用，通过矩阵链的严重延迟的节段运动来解释。此外，瞬时粘弹性分析显示，改性的CNT-PS对流动引起的BCP结构取向具有更大的结构恢复速率。结果表明，动态机械热分析可以提供有价值的见解，了解CNT掺入对BCP纳米复合材料样品的微观结构的作用。因此，CNT的存在对微观结构显影具有显着的促进作用，与退火相当。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24310/'>《Macromolecular chemistry and physics》</a> <b style="margin: 0 2px;">|</b><span>2017年第22期</span><b style="margin: 0 2px;">|</b><span>共1页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hasanabadi Noushin&option=202" target="_blank" rel="nofollow">Hasanabadi Noushin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nazockdast Hossein&option=202" target="_blank" rel="nofollow">Nazockdast Hossein;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gajewska Bernadetta&option=202" target="_blank" rel="nofollow">Gajewska Bernadetta;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Balog Sandor&option=202" target="_blank" rel="nofollow">Balog Sandor;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gunkel Ilja&option=202" target="_blank" rel="nofollow">Gunkel Ilja;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bruns Nico&option=202" target="_blank" rel="nofollow">Bruns Nico;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lattuada Marco&option=202" target="_blank" rel="nofollow">Lattuada Marco;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Polymer EngineeringAmirkabir University of Technology15875‐4413 Tehran Iran;</p> <p>Department of Polymer EngineeringAmirkabir University of Technology15875‐4413 Tehran Iran;</p> <p>Adolphe Merkle InstituteUniversity of FribourgChemin des Verdiers 4 CH‐1700 Fribourg Switzerland;</p> <p>Adolphe Merkle InstituteUniversity of FribourgChemin des Verdiers 4 CH‐1700 Fribourg Switzerland;</p> <p>Adolphe Merkle InstituteUniversity of FribourgChemin des Verdiers 4 CH‐1700 Fribourg Switzerland;</p> <p>Adolphe Merkle InstituteUniversity of FribourgChemin des Verdiers 4 CH‐1700 Fribourg Switzerland;</p> <p>Department of ChemistryUniversity of FribourgChemin du Musée 9 CH‐1700 Fribourg Switzerland;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1185.html" title="高分子化学（高聚物）">高分子化学（高聚物）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ATRP&option=203" rel="nofollow">ATRP;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CNT&option=203" rel="nofollow">CNT;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=DMTA&option=203" rel="nofollow">DMTA;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rheological characterization&option=203" rel="nofollow">rheological characterization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=SEBS block copolymer&option=203" rel="nofollow">SEBS block copolymer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=structural development&option=203" rel="nofollow">structural development;</a> </p> <div class="translation"> 机译：atrp;cnt;dmta;流变表征;SEBS嵌段共聚物;结构发展; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023544998.html">Structural Behavior of Cylindrical Polystyrene‐ <i xmlns="http://www.wiley.com/namespaces/wiley">blockblock ‐Poly(ethylene‐butylene)‐ <i xmlns="http://www.wiley.com/namespaces/wiley">blockblock ‐Polystyrene (SEBS) Triblock Copolymer Containing MWCNTs: On the Influence of Nanoparticle Surface Modification</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hasanabadi Noushin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hasanabadi Noushin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nazockdast Hossein&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nazockdast Hossein,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gajewska Bernadetta&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gajewska Bernadetta,</a> <a href="/journal-foreign-24310/" target="_blank" rel="nofollow" class="tuijian_authcolor">Macromolecular chemistry and physics .</a> <span>2017</span><span>,第22期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：圆柱聚苯乙烯 - <i xmlns =“http://www.wiley.com/namespaces/wiley”> block </ i>块-poly（亚乙烯 - 丁烯） - <i xmlns =“http：// www .wiley.com /命名空间/ wiley“>嵌段</ i>嵌段 - 含有mwcnts的三嵌段（Sebbs）三嵌段共聚物：关于纳米颗粒表面改性的影响</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020726057.html">RAFT synthesis of polystyrene‐ <i xmlns="http://www.wiley.com/namespaces/wiley">blockblock ‐poly(polyethylene glycol monomethyl ether acrylate) for zinc phthalocyanine‐loaded polymeric micelles as photodynamic therapy photosensitizers</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Obata Makoto&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Obata Makoto,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tanaka Shuto&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tanaka Shuto,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mizukoshi Hiroshi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mizukoshi Hiroshi,</a> <a href="/journal-foreign-35621/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part A. Polymer Chemistry .</a> <span>2018</span><span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：聚苯乙烯 - <i Xmlns =“http://www.wiley.com/namespace/wiley”>块状 - 磷酸锌酞菁加载的聚合物胶束作为光动力治疗的聚（聚乙二醇单甲基醚丙烯酸酯）作为光动力治疗 光敏剂</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025810988.html">A roadmap for poly(ethylene oxide)‐ <i xmlns="http://www.wiley.com/namespaces/wiley">blockblock ‐poly‐ε‐caprolactone self‐assembly in water: Prediction, synthesis, and characterization</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ianiro Alessandro&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ianiro Alessandro,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Patterson Joseph&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Patterson Joseph,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=González García álvaro&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">González García álvaro,</a> <a href="/journal-foreign-35627/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part B. Polymer Physics .</a> <span>2018</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：聚（环氧乙烷）的路线图 - <i xmlns =“http://www.wiley.com/namespaces/wiley”> block </ i>块 - ε-己内酯自我组装在水中：预测，合成 和表征</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100028251822.html">Structural behavior of cylindrical polystyrene-block-poly(ethylene-butylene)-block-polystyrene (SEBS) triblock copolymer containing MWCNTs: on the influence of nanoparticle surface modification</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hasanabadi Noushin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hasanabadi Noushin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nazockdast Hossein&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nazockdast Hossein,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gajewska Bernadetta&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gajewska Bernadetta,</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含碳纳米管的圆柱形聚苯乙烯-嵌段-聚（乙烯-丁烯）-嵌段-聚苯乙烯（SEBS）三嵌段共聚物的结构行为：对纳米粒子表面改性的影响</span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704023544998','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche"> <!-- <a href="javascript:void(0);" onclick="link_analysis('/shoppingcart/auth/list.html',this)">购物车</a>--> </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704023544998down" data-source="7," data-out-id="WUjyxqf00jfcN8MMpsV3RA==," data-f-source-id="7" data-title="Structural Behavior of Cylindrical Polystyrene‐ <i xmlns='http://www.wiley.com/namespaces/wiley'>blockblock ‐Poly(ethylene‐butylene)‐ <i xmlns='http://www.wiley.com/namespaces/wiley'>blockblock ‐Polystyrene (SEBS) Triblock Copolymer Containing MWCNTs: On the Influence of Nanoparticle Surface Modification" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="24310" id="journalid"> <input type="hidden" value="4" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Structural Behavior of Cylindrical Polystyrene‐ <i xmlns='http://www.wiley.com/namespaces/wiley'>blockblock ‐Poly(ethylene‐butylene)‐ <i xmlns='http://www.wiley.com/namespaces/wiley'>blockblock ‐Polystyrene (SEBS) Triblock Copolymer Containing MWCNTs: On the Influence of Nanoparticle Surface Modification"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.7"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>