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Ionic Dependence of Gelatin Hydrogel Architecture Explored Using Small and Very Small Angle Neutron Scattering Technique

机译：使用小小小角度中子散射技术探索明胶水凝胶架构的离子依赖性

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Abstract > The hierarchical structure of gelatin hydrogels mimics a natural extracellular matrix and provides an optimized microenvironment for the growth of 3D structured tissue analogs. In the presence of metal ions, gelatin hydrogels exhibit various mechanical properties that are correlated with the molecular interactions and the hierarchical structure. The structure and structural response of gelatin hydrogels to variation of gelatin concentration, pH, or addition of metal ions are explored by small and very small angle neutron scattering over broad length scales. The measurements of the hydrogels reveal the existence of a two‐level structure of colloid‐like large clusters and a 3D cage‐like gel network. In the presence of Fe 3+ ions the hydrogels show a highly dense and stiff network, while Ca 2+ ions have an opposite effect. The results provide important structural insight for improvement of the design of gelatin based hydrogels and are therefore suitable for various applications. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</标题> >明胶水凝胶的层次结构模拟天然细胞外基质，为生长提供了优化的微环境3D结构化组织类似物。在金属离子的存在下，明胶水凝胶具有与分子相互作用和分级结构相关的各种机械性能。通过宽长度尺度的小和非常小的角度散射探索明胶水凝胶与明胶浓度，pH的变化的结构和结构响应，pH或加入金属离子的加入。水凝胶的测量揭示了胶体状大簇的两层结构和3D笼状凝胶网络的存在。在Fe 3 + </ sup>离子的存在下，水凝胶显示出高度密集和坚硬的网络，而CA 2 + </ sup>离子具有相反的效果。结果为改善明胶基水凝胶的设计提供了重要的结构洞察，因此适用于各种应用。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24307/'>《Macromolecular bioscience》</a> <b style="margin: 0 2px;">|</b><span>2018年第6期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Baohu&option=202" target="_blank" rel="nofollow">Wu Baohu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Siglreitmeier Maria&option=202" target="_blank" rel="nofollow">Siglreitmeier Maria;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Debus Christian&option=202" target="_blank" rel="nofollow">Debus Christian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schwahn Dietmar&option=202" target="_blank" rel="nofollow">Schwahn Dietmar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C?lfen Helmut&option=202" target="_blank" rel="nofollow">C?lfen Helmut;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pipich Vitaliy&option=202" target="_blank" rel="nofollow">Pipich Vitaliy;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Jülich Centre for Neutron Science (JCNS) at Heinz Maier‐Leibnitz Zentrum (MLZ)Forschungszentrum JülichLichtenbergstr. 1 85748 Garching Germany;</p> <p>Department of ChemistryUniversity of KonstanzUniversitaetsstr 10 Konstanz 78457 Germany;</p> <p>Department of ChemistryUniversity of KonstanzUniversitaetsstr 10 Konstanz 78457 Germany;</p> <p>Forschungs‐Neutronenquelle Heinz Maier‐Leibnitz (FRM II)Technische Universit?t MünchenLichtenbergstr 1 Garching 85748 Germany;</p> <p>Department of ChemistryUniversity of KonstanzUniversitaetsstr 10 Konstanz 78457 Germany;</p> <p>Jülich Centre for Neutron Science (JCNS) at Heinz Maier‐Leibnitz Zentrum (MLZ)Forschungszentrum JülichLichtenbergstr. 1 85748 Garching Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1185.html" title="高分子化学（高聚物）">高分子化学（高聚物）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gelatin hydrogels&option=203" rel="nofollow">gelatin hydrogels;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ionic dependence&option=203" rel="nofollow">ionic dependence;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=SANS&option=203" rel="nofollow">SANS;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=VSANS&option=203" rel="nofollow">VSANS;</a> </p> <div class="translation"> 机译：明胶水凝胶;离子依赖;SAN;vsans; 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