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Study of Miscibility, Crystallization, and Biodegradation of Casting Films of Poly(butylene succinate-co-adipate) and Poly(e-Caprolactone) Blends

机译:聚(丁二酸酯 - 共己酸酯)和聚(E-己内酯)共混物的铸造薄膜混溶性,结晶和生物降解研究

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This work presents the miscibility and crystallization evaluations of poly (butylene succinate-co-adipate) (PBSA) and poly (e-caprolactone) (PCL) blends by dynamic-mechanical thermal analysis (DMTA) and polarized light optical microscopy (PLOM), as well as the assessment of biodegradability of pure polymers and its blends in compost soil. DMTA and PLOM results confirmed the immiscibility of the blends and pointed to the possibility of compatibility between the blend components of various compositions. Soil burial biodegradation assay demonstrates that the blends showed a higher biodegradation rate than pure polymers. Overall, results indicate that it is possible to improve mechanical properties by blending PBSA with PCL, without losing biodegradation properties.
机译:该工作介绍了聚(丁二烯 - 共己酸酯)(PBSA)和聚(E-己内酯)(PCL)混合通过动态机械热分析(DMTA)和偏振光光学显微镜(PLOM)的混溶性和结晶评价(PCL), 除了纯聚合物的生物降解性及其在堆肥土壤中的混合物的评估。 DMTA和PLOM结果证实了混合物的不混溶性,并指出了各种组合物的共混组分之间的相容性的可能性。 土壤埋葬生物降解测定表明,共混物显示出比纯聚合物更高的生物降解率。 总体而言,结果表明可以通过将PBSA与PCL混合,而不会损失生物降解性能来改善机械性能。

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