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Effect of the Joncryl? ADR Compatibilizing Agent in Blends of Poly(butylene adipate-co-terephthalate)/ Poly(lactic acid)

机译:joncryl的影响? 聚合物化剂在聚(丁烯己二酸丁二醇酯)/聚(乳酸)中的共混物

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摘要

The growing search for biodegradable products contributes to the development of new materials. In this work, the effect of the Joncryl1 ADR chain extender on poly(butylene adipate-co-terephthalate)/poly(lactic acid) blends was investigated. The mechanical, thermal, and morphological properties and the contact angle of the blends were also studied. The addition of the chain extender can either improve the adhesion between the phases or act as a stress concentrator, depending on the proportion of PLA present in the blend. However, in all samples, the elongation at break was increased. This behavior is also observed in the morphology of the blends, changing the shape of the PLA particles, from spherical to ellipsoid phase. However, in the proportion used (0.5 wt%), the chain extender was not enough to increase the adhesion between the phases of the blends, just the dispersion of the PLA particles. Besides, it is possible to observe that the higher the PLA content in the PBAT mixture, the lower wettability surface of the blends is reached.
机译:越来越多的可生物降解产品的搜索有助于开发新材料。在这项工作中,研究了Joncryl1 ADR链增量剂对聚(丁烯己二酸丁二醇酯)/聚(乳酸)共混物的影响。还研究了机械,热和形态特性和混合物的接触角。根据共混物中存在的PLA的比例,添加链增量剂可以改善相或用作应力浓缩器之间的粘附性。然而,在所有样品中,突破的伸长率增加。在混合物的形态中也观察到这种行为,从球形到椭圆形相改变PLA颗粒的形状。然而,在所使用的比例(0.5wt%)中,扩链剂不足以增加共混物的相之间的粘合,只是PLA颗粒的分散。此外,可以观察到PBAT混合物中的PLA含量越高,达到共混物的较低润湿性表面。

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