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Impact of large sized inertinite particles on thermo-swelling and volatile release of coking coals

机译:大型偏心颗粒对焦化煤热膨胀和挥发释放的影响

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摘要

A reflux classifier system was employed to concentrate large sized inertinite-rich particles (1.6-2.0 mm) from two different ranked coking coals A and B. The impact of these concentrates on swelling, permeability and volatile evolution rates of another two coking coals C and D was investigated using the Computer Aided Thermal Analysis (CATA) and Dynamic Elemental Thermal Analysis (DETA) techniques. The results indicated that the concentrated inertinite-rich particles contained inertinite up to 75% for both coals A and B. When 25% inertinite particles were blended with 75% coal C or D by mass, the low rank inertinite concentrates A caused higher extents of effect on swelling and permeability than the high rank inertinite concentrates B, leading to higher softening temperatures with smaller plastic ranges. During swelling, inertinite concentrates B can compress volatile evolution rates of both coals C and D, however, inertinite concentrates A promoted volatile evolution rate of coal C. Concentrates from both coals A and B can compress the utilization of volatiles for driving swelling, the blend containing concentrate A used nearly half of volatiles that coals C and D themselves used for driving swelling. This study suggested that the additive internite concentrates not only provided a pathway for gas diffusion, but also interacted with the blended coals, which affected thermoplasticity of the whole blends.
机译:采用回流分类器系统从两种不同的排名焦化煤A和B集中大尺寸的富能丰富的颗粒(1.6-2.0mm)。这些浓缩物对另外两种焦化煤的溶胀,渗透性和挥发性进化率的影响。使用计算机辅助热分析(CATA)和动态元素热分析(DETA)技术来研究D。结果表明,浓缩的富含含量富含素的颗粒含有高达75%的煤A和B.当25%惯性颗粒与75%煤C或D质量混合时,低等级占浓缩率造成的较高范围对溶胀性和渗透性的影响比高级偏心浓缩物B,导致较小的塑料范围更加软化温度。在膨胀期间,惰性素浓缩物B可以压缩煤C和D的挥发性进化速率,然而,Inertinite浓缩煤C的促进的挥发性演化速率。来自煤α和B的浓缩物可以压缩利用挥发物用于驱动膨胀,混合含有浓缩物A使用的近一半的挥发物,其煤C和D本身用于驱动膨胀。该研究表明,添加剂型浓缩物不仅为气体扩散的途径提供了途径,而且还与混合煤相互作用,这影响了整个共混物的热塑性。

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