Hot‐Pressed Hybrid Electrodes Comprising Silver Nanowires and Conductive Polymers for Mechanically Robust, All‐Doctor‐Bladed Semitransparent Organic Solar Cells

Koppitz Manuel; Wegner Eduard; R?dlmeier Tobias; Colsmann Alexander

摘要

Abstract > Future low‐cost, high‐throughput production of organic solar cells in roll‐to‐roll printing processes calls for all‐solution‐processable device architectures. Mechanical flexibility and robustness are mandatory to roll the solar foils during printing and to eventually comply with certain end‐user requirements. Here, we report on semitransparent organic solar cells, comprising top and bottom silver nanowire (AgNW) electrodes that were embedded into conductive poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The devices exhibited excellent robustness in bending experiments with radii of 5 and 2.5?mm as well as upon folding. To avoid short circuits from nanowires that could stick out of the bottom electrodes, the PEDOT:PSS:AgNW layers were flattened by hot‐pressing after deposition. All solar cells were fabricated in air by doctor blading and exhibited a clear (haze‐free) transparency due to the absence of bus bars. On photoactive areas of 0.5?cm 2 , power conversion efficiencies of 3.8?% were obtained. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >未来低-Cost，高通量生产的滚动印刷工艺中有机太阳能电池的生产呼吁所有解决方案可加工的设备架构。机械灵活性和鲁棒性是强制性的，在打印过程中卷起太阳能箔，最终符合某些最终用户要求。这里，我们报告半透明有机太阳能电池，包括嵌入导电聚（3,4-亚乙二氧基噻吩）的顶部和底层银纳米线（AgNw）电极：聚（苯乙烯磺酸盐）（PEDOT：PSS）。该器件在弯曲实验中表现出优异的稳健性，其半径为5和2.5Ωmm以及折叠。为了避免纳米线的短路，可以伸出底部电极，PEDOT：PSS：PSS：沉积后通过热压扁平地扁平。由于缺乏汇流条，通过博士展示，通过博士血压展示所有太阳能电池在空中制造，并且由于没有汇流条而发出明显的（无阴霾）透明度。在0.5Ωcm 2 </ sup>的光活性区域上，获得3.8〜％的功率转换效率。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22585/'>《Energy Technology: Generation,Conversion,Storage,Distribution》</a> <b style="margin: 0 2px;">|</b><span>2018年第7期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Koppitz Manuel&option=202" target="_blank" rel="nofollow">Koppitz Manuel;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wegner Eduard&option=202" target="_blank" rel="nofollow">Wegner Eduard;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=R?dlmeier Tobias&option=202" target="_blank" rel="nofollow">R?dlmeier Tobias;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Colsmann Alexander&option=202" target="_blank" rel="nofollow">Colsmann Alexander;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Light Technology Institute (LTI)Karlsruhe Institute of Technology (KIT)Engesserstrasse 13 76131 Karlsruhe Germany;</p> <p>Light Technology Institute (LTI)Karlsruhe Institute of Technology (KIT)Engesserstrasse 13 76131 Karlsruhe Germany;</p> <p>Light Technology Institute (LTI)Karlsruhe Institute of Technology (KIT)Engesserstrasse 13 76131 Karlsruhe Germany;</p> <p>Light Technology Institute (LTI)Karlsruhe Institute of Technology (KIT)Engesserstrasse 13 76131 Karlsruhe Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/233.html" title="能源与动力工程">能源与动力工程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=all-solution processing&option=203" rel="nofollow">all-solution processing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organic solar cells&option=203" rel="nofollow">organic solar cells;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photovoltaics&option=203" rel="nofollow">photovoltaics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polymers&option=203" rel="nofollow">polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=printed electronics&option=203" rel="nofollow">printed electronics;</a> </p> <div class="translation"> 机译：全解决方案加工;有机太阳能电池;光伏;聚合物;印刷电子产品; 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