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Magnetite Nanoparticles Bonded Carbon Quantum Dots Magnetically Confined onto Screen Printed Carbon Electrodes and their Performance as Electrochemical Sensor for NADH

机译：磁铁矿纳米颗粒粘合碳量子点磁共限制在丝网印刷碳电极上及其作为NADH电化学传感器的性能

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Abstract > Hybrid magnetite/carbon quantum dots (MagNP/C‐dots) were prepared and their characterization performed by high resolution transmission electron microscopy (HR‐TEM), X‐ray diffraction (XRD) and X‐ray photoelectron spectroscopy (XPS). Because of their suitable magnetization and electrochemical properties, they were used as versatile electrode modifiers after magnetically confining onto screen printed carbon electrodes (SPE), with the aid of a miniature external magnet. The reported strategy introduces a convenient procedure for assembling modified electrodes, since the nanoparticles can be easily released by removing the magnet. The non‐enzymatic magnetic biosensor showed excellent performance in the determination of NADH at the concentration range 2×10 ?7 to 5×10 ?6 ?mol?L ?1 , exhibiting a sensitivity of 0.15?μmol?L ?1 and detection limit of 20?nmol?L ?1 . The MagNP/C‐dots/SPE sensor was also successfully applied for the determination of NADH in serum samples. The interference of typical biological molecules has also been investigated. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> >混合磁铁矿/碳量子点（Magnp / C点）制备并通过高分辨率透射电子显微镜（HR-TEM），X射线衍射（XRD）和X射线光电子谱（XPS）进行其表征。由于它们合适的磁化和电化学性能，借助于微型外部磁体在丝网印刷的碳电极（SPE）上之后，它们用作通用电极改性剂。报告的策略介绍了用于组装改性电极的方便步骤，因为通过去除磁体可以容易地释放纳米颗粒。非酶促磁性生物传感器在浓度范围内的浓度范围内的NADH测定2×10 Δ7</ sup>至5×10 Δ6</ sup>Δωl时，在NADH的测定中表现出优异的性能。 ？1 </ sup>，表现出0.15Ωμmol？l α1</ sup>和20≤nmolα1α1</ sup>的敏感性。 Magnp / C-Dots / SPE传感器也成功地应用于血清样品中NADH的测定。还研究了典型的生物分子的干扰。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2017年第8期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Canevari Thiago C.&option=202" target="_blank" rel="nofollow">Canevari Thiago C.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cincotto Fernando H.&option=202" target="_blank" rel="nofollow">Cincotto Fernando H.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gomes Delmarcio&option=202" target="_blank" rel="nofollow">Gomes Delmarcio;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Landers Richard&option=202" target="_blank" rel="nofollow">Landers Richard;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Toma Henrique E.&option=202" target="_blank" rel="nofollow">Toma Henrique E.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Engineering SchoolPresbyterian University Mackenzie01302-907 S?o Paulo SP Brazil;</p> <p>Department ChemistryFederal University of S?o Carlos13565-905 S?o Carlos SP Brazil;</p> <p>Institute of ChemistryUniversity of S?o Paulo05508-000 S?o Paulo SP Brazil;</p> <p>Institute of physicUniversity of Campinas13560-970 Campinas SP Brazil;</p> <p>Institute of ChemistryUniversity of S?o Paulo05508-000 S?o Paulo SP Brazil;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bioelectrochemistry&option=203" rel="nofollow">Bioelectrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=NADH&option=203" rel="nofollow">NADH;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nanoelectrochemistry&option=203" rel="nofollow">Nanoelectrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Magnetic nanoparticles&option=203" rel="nofollow">Magnetic nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sensors&option=203" rel="nofollow">Sensors;</a> </p> <div class="translation"> 机译：生物电化学;NADH;纳米电化学;磁性纳米粒子;传感器; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023174665.html">Magnetite Nanoparticles Bonded Carbon Quantum Dots Magnetically Confined onto Screen Printed Carbon Electrodes and their Performance as Electrochemical Sensor for NADH</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Canevari Thiago C.&option=202" 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