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J. Heyrovsky's Oscillographic Polarography. Roots of Present Chronopotentiometric Analysis of Biomacromolecules

机译：J. Heyrovsky的示波器极谱图。生物致摩托的速度计量分析

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Abstract >In 1941?J. Heyrovsky invented Oscillographic Polarography (OP) with controlled alternating current (a.c.). The method was developed during the World War and the first commercially available instruments for OP were produced in Czechoslovakia at the beginning of the 1950’s. Such instruments offered derivative and cyclic OP curves allowing simple analysis of various compounds and stimulated the publication of hundreds of papers. Thanks to OP, electrochemical analysis of DNA started already in 1958. According to the present nomenclature, OP can be denominated as a.c. chronopotentiometry. Surprisingly, authors who later described derivative and cyclic chronopotentiometry did not consider J. Heyrovsky’s OP methodology in their work. Present electrochemical studies of biomacromolecules take advantage of modern instruments for constant current chronopotentiometric stripping, allowing DNA and protein structure‐sensitive analysis. Recent progress in these studies is reviewed. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> > 1941？j。 Heyrovsky发明了具有受控交流电流（A.C.）的示波器极谱仪（OP）。该方法是在世界大战期间开发的，在20世纪50年代初，在捷克斯洛伐克生产的第一个商业上可用的仪器。这些仪器提供了衍生物和循环型曲线，允许简单地分析各种化合物并刺激数百篇论文的出版物。由于OP，DNA的电化学分析已于1958年开始。根据目前的命名，OP可以根据A.C.时间计量测量测量术。令人惊讶的是，后来描述了衍生物和循环计时表的作者没有考虑J. Heyrovsky在工作中的op方法。目前对生物主义的电化学研究利用现代仪器用于恒流计时表剥离，允许DNA和蛋白质结构敏感性分析。综述了这些研究的最新进展。</ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第7期</span><b style="margin: 0 2px;">|</b><span>共12页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pale?ek Emil&option=202" target="_blank" rel="nofollow">Pale?ek Emil;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heyrovsky Michael&option=202" target="_blank" rel="nofollow">Heyrovsky Michael;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dor?ák Vlastimil&option=202" target="_blank" rel="nofollow">Dor?ák Vlastimil;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Biophysics of the CASKrálovopolská 135 612 65 Brno Czech Republic;</p> <p>J. Heyrovsky Institute of Physical Chemistry of the CASDolej?kova 2155/3 182 23 Prague 8 Czech Republic;</p> <p>Institute of Biophysics of the CASKrálovopolská 135 612 65 Brno Czech Republic;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Oscillographic polarography with controlled a.c.&option=203" rel="nofollow">Oscillographic polarography with controlled a.c.;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Constant current chronopotentiometric stripping&option=203" rel="nofollow">Constant current chronopotentiometric stripping;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Catalytic hydrogen evolution in biomacromolecules at mercury electrodes&option=203" rel="nofollow">Catalytic hydrogen evolution in biomacromolecules at mercury electrodes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Protein structure-sensitive analysis&option=203" rel="nofollow">Protein structure-sensitive analysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Intrinsic electrocatalysis in DNA&option=203" rel="nofollow">Intrinsic electrocatalysis in DNA;</a> </p> <div class="translation"> 机译：具有受控A.C的示波器极谱法;恒定电流时间计量剥离;汞电极的生物致摩托溶液中的催化氢气进化;蛋白质结构敏感性分析;DNA中的固有电常放分析; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023174442.html">J. 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