Early to Mid-Miocene syn-extensional massive silicic volcanism in the Pannonian Basin (East-Central Europe): Eruption chronology, correlation potential and geodynamic implications

摘要

Formation and evolution of the Pannonian Basin as part of the Mediterranean region was accompanied by eruptions of compositionally diverse magmas during the Neogene to Quaternary. The long-lasting magmatic activity began with some of the most voluminous silicic eruptions in Europe for the last 20 Myr. This paper describes the eruption chronology of this volcanic activity using new, high-quality zircon U-Pb dates, and provides the first estimates on the volume and areal distribution of the volcanic products, characterizes the magma composition and discusses the silicic magmatism in a region, where the continental lithosphere underwent significant extension. A thorough zircon geochronological study was conducted on samples collected from ignimbrites and pyroclastic fall deposits exposed in the Bukkalja Volcanic Field. In-situ LA-ICP-MS analysis on zircon grains provided a fast, cheap and accurate method for such detailed geochronological work, where the volcanic products occur in scattered outcrops that often have poor stratigraphic constraints. The interpreted eruption ages were determined from the youngest zircon age population within the samples and this methodology was validated by new single zircon CA-ID-TIMS dates and sanidine Ar-Ar ages. The volcanism covers about 4 Myrs, from 18.2 Ma to 14.4 Ma and involved at least eight eruptive phases. Within this, four large eruption events were recognized at 14.358 +/- 0.015 Ma (Harsany ignimbrite), 14.880 +/- 0.014 Ma (Demjen ignimbrite), 16.816 +/- 0.059 Ma (Bogacs unit) and 17.055 +/- 0.024 Ma (Mango ignimbrite), which are found in areas across the Pannonian Basin and elsewhere in central Europe. Considering all the potential sources of silicic ash found in the Paratethys sub-basins around the Pannonian Basin and along the northern Alps and in central Italy, we suggest that they were probably derived almost exclusively from the Pannonian Basin as shown by zircon U-Pb dates presented in this paper and published comparab