Thermal, Tensile, Electrical, Dynamic Mechanical Thermal and Rheological Properties of Polyvinylidene Fluoride and Fluoroelastomer Composites Filled with Carbon Black

摘要

The present work was focused on studying the effects of different CB loadings on the rheological, thermal, tensile, dynamic mechanical and electrical properties of polyvinylidenefluoride (PVDF) and FKM composites. To these ends, the CB grade and method chosen for compound preparation were CB (N330) and melt mixing, respectively. The composites were melt blended with CB at 190 degrees C in an internal mixer, after which the properties of filled and unfilled composites were compared. The presence of CB improved the mechanical properties, such as the Young's modulus and tensile strength, and increased thermal stability given the high thermal stability of CB and the interaction between the CB particles and the polymer matrices. The dynamic mechanical thermal analysis (DMTA) showed the glass transition temperatures of the composites. The analysis also revealed that the area under the loss tangent (tan delta) peak decreased and that the tan delta temperature of the rubber phase increased with CB loading. The increase in the electrical conductivity of the composites under different CB loadings was also examined, and the percolation threshold of conductive thermoplastic vulcanizate composite based on conductive CB was observed. The effect of CB and its content on rheological behavior of the PVDF/FKM blends was studied and the experimental data was correlated by a physical model named General Equation Model (GEM). A relation between rheology and conductivity of the blends with filler percolation was found.