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Preparation of MoS2/Ti3C2Tx composite as anode material with enhanced sodium/lithium storage performance

机译:用增强钠/锂储存性能的阳极材料制备MOS2 / TI3C2TX复合材料

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摘要

MoS2/Ti3C2Tx composite was synthesized by a facile one-step hydrothermal method without further annealing process. When tested as anode material for sodium-ion batteries, it exhibited a high reversible capacity of 331 mA h g(-1) at 100 mA g(-1) after 70 cycles with only 0.058% decay per cycle. When tested as anode material for lithium-ion batteries, it exhibited a reversible capacity of 614.4 mA h g(-1) at 100 mA g(-1) after 70 cycles with only 0.05% decay per cycle. Moreover, compared with pristine MoS2 and pure Ti3C2Tx, the composite had better rate performance and faster ion diffusion kinetics, which might be caused by the as-prepared composite material having relatively rough surface, more active sites and more convenient diffusion paths.
机译:MOS2 / TI3C2Tx复合材料通过容易的一步水热法合成,无需进一步退火工艺。 当测试为钠离子电池的阳极材料时,在70次循环后,在每循环衰减0.058%衰减后,它在100 mA g(-1)下表现出331mA Hg(-1)的高可逆容量。 当作为锂离子电池的阳极材料进行测试时,在70次循环后,在每循环的0.05%衰减的70次循环后,它在100mA g(-1)下表现出614.4 mA H(-1)的可逆容量。 此外,与原始MOS2和纯TI3C2Tx相比,复合材料具有更好的速率性能和更快的离子扩散动力学,这可能由具有相对粗糙表面,更具活性位点和更方便的扩散路径的由制备的复合材料引起。

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  • 来源
    《Inorganic Chemistry Frontiers》 |2019年第1期|共9页
  • 作者单位

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

    Southwest Univ Fac Mat &

    Energy Minist Educ Key Lab Luminescent &

    Real Time Analyt Chem Chongqing 400715 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 无机化学;
  • 关键词

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