Free‐Radical‐Promoted Alkenylation of C(sp3)?H Bond in Chloroalkane with Cinnamic Acid and β‐Nitrostyrene

摘要

Abstract > We demonstrated herein a free‐radical alkenylation of the C( sp 3 )?H bond in 1,2‐dichloroethane with cinnamic acid and β ‐nitrostyrene. This method not only provides a facile approach to chloroalkylated styrenes, but also would be instructive for halogen‐atom directing selective functionalization of inert C( sp 3 )?H bond. > <blockFixed type="graphic"> <mediaResourceGroup> <mediaResource alt="image" href="urn:x-wiley:16154150:media:adsc202000215:adsc202000215-toc-0001"/> </mediaResourceGroup> </blockFixed> </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 我们在此证明了C的自由基链烯化酶（ sp </ i> 3 </ sup> ）γ-二氯乙烷与肉桂酸和 β</ i> -Nitrostyrene。该方法不仅提供了氯烷基化的苯乙烯的容易方法，而且对惰性C的选择性官能化进行卤素原子（ sp </ i> 3 </ sup> ）？H键。 </ p> > <blockfixed type =“图形”> <mediaresourcegroup> <mediareSource Alt =“图像”Href =“URN：X-Wiley：16154150：介质：ADSC202000215：ADSC202000215-TOC-0001”/> </ mediaresourcegroup> </ blockfixed> </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19407/'>《Advanced synthesis & catalysis》</a> <b style="margin: 0 2px;">|</b><span>2020年第11期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/238.html" title="化学工业">化学工业;</a><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a><a href="https://www.zhangqiaokeyan.com/clc/7777.html" title="化学反应过程">化学反应过程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Free-radical&option=203" rel="nofollow">Free-radical;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C?H activation&option=203" rel="nofollow">C?H activation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Decarboxylation&option=203" rel="nofollow">Decarboxylation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Haloalkane&option=203" rel="nofollow">Haloalkane;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cinnamic acid&option=203" rel="nofollow">Cinnamic acid;</a> </p> <div class="translation"> 机译：自由基;C？H激活;脱羧;卤代甲烷;肉桂酸; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022691411.html">Free‐Radical‐Promoted Alkenylation of C(sp3)?H Bond in Chloroalkane with Cinnamic Acid and β‐Nitrostyrene</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-19407/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced synthesis & catalysis .</a> <span>2020</span><span>,第11期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用肉桂酸和β-硝基苯乙烯在氯烷烃中促进的自由基促进的C（SP3）αH键合</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070405732409.html">Iron-catalyzed direct alkenylation of sp~3(C-H) bonds via decarboxylation of cinnamic acids under ligand-free conditions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hailong Yang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hailong Yang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hong Yan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hong Yan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Peng Sun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Peng Sun </a> <a href="/journal-foreign-23609/" target="_blank" rel="nofollow" class="tuijian_authcolor">Green chemistry .</a> <span>2013</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在无配体条件下肉桂酸的脱羧，铁催化sp〜3（C-H）键的直接烯基化</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_journal-the-american-chemical-society_thesis/0204112052762.html">Enantioselective Free Radical Carbon-Carbon Bond Forming Reactions: Chiral Lewis Acid Promoted Acyclic Additions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jason Hongliu Wu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jason Hongliu Wu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rumen Radinov&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rumen Radinov,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ned A. 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