Quantifying the extent of flowback of hydraulic fracturing fluids using chemical and isotopic tracer approaches

摘要

Hydraulic fracturing technologies have facilitated the rapid development of shale gas and other unconventional hydrocarbon resources throughout the world. Following hydraulic fracturing operations, a large quantity of water flows back to the surface. Understanding the provenance and composition of this returned water is therefore of paramount importance in order to optimize the recycling and reuse of the millions of litres of wastewater generated by hydraulic fracturing and to reduce freshwater consumption. Here we report flowback and produced fluids data obtained from a horizontal well in a low permeability reservoir within the Montney formation in Alberta, Canada. The reservoir was fractured with a mixture of nitrogen and water and the returned water was sampled 24 times during the first week of flowback and once after more than one year of production. The samples were analyzed for concentrations of major ions and for the stable isotope composition of water. The TDS (total dissolved solids) of the samples increased rapidly from 395 mg/L for the injected water to 50,000 mg/L after two days and 96,000 mg/L at the end of the first week of flowback. At the same time, delta H-2 values increased from -142 parts per thousand to -113 parts per thousand and delta O-18 values increased from -18.3 parts per thousand to -9.8 parts per thousand. After more than one year, TDS reached 204,000 mg/L while delta H-2 and delta O-18 values further increased to -68 parts per thousand and + 2.7 parts per thousand. The salinity of the returned water is shown to be the result of the mixing between the highly saline formation water initially present in the reservoir before hydraulic fracturing, with the fresh water used for hydraulic fracturing. The presented mathematical model allows the calculation of the amount of fracturing fluid recovered as well as the quantity of saline formation water produced and reveals that most of the injected water is imbibed in the host rock of the producing