Supercritical Fenton Oxidation: A New Method for Total Organic Carbon Measurement

摘要

A new method for total organic carbon (TOC) measurement was established based on supercritical Fenton oxidation. The organic pollutants in wastewater were oxidized to carbon dioxide in supercritical water by Fenton reagents that was detected using a nondispersive infrared detector. The influence of temperature from 380 to 480 degrees C, oxidant coefficient from 1 to 20, pH from 2.2 to 5.2, and Fe2+ concentration from 0.2 to 0.8mgL(-1) was characterized; the optimal conditions were at 420 degrees C, an oxidant coefficient n5, a pH of 4.4, and Fe2+ concentration of 0.8mgL(-1). Using these parameters, the recovery of potassium hydrogen phthalate exceeded 98.2%. The introduction of Fenton oxidation based on supercritical water lowered the temperature and reduced the oxidant coefficient required for TOC determination.