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Synergistic effect of phosphorus‐containing silane coupling agent with alumina trihydrate in ethylene‐vinyl acetate composites

机译:含磷硅烷偶联剂与氧化铝三水合物在乙烯 - 乙酸乙烯酯复合材料中的协同作用

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摘要

Abstract > A new interfacial modifier containing silicon and phosphorus has been developed to improve the flame retardancy and mechanical properties of ethylene‐vinyl acetate ( <fc>EVA</fc> )/alumina trihydrate ( <fc>ATH</fc> ) composites. The <fc>EVA</fc> / <fc>ATH</fc> composites were prepared via blending <fc>EVA</fc> pellets with different kinds of <fc>ATH</fc> particles. The results showed a synergistic effect of phosphorus‐containing silane coupling agent ( <fc>DOSA</fc> ) and <fc>ATH</fc> particles on the flame retardancy of <fc>EVA</fc> composites. When compared with pure <fc>EVA</fc> of 19.1, the limiting oxygen index ( <fc>LOI</fc> ) value was increased to 31.4. This was the result of the formation of a charred layer and the enhanced compatibilities between inorganic particles and polymer matrix. The experimental results also showed that the modified <fc>ATH</fc> particles by using synthesized <fc>DOSA</fc> led to an increase in mechanical properties. The improvement on the mechanical and thermal properties of <fc>EVA</fc> composites was mostly attributed to the better dispersion ability of the modified <fc>ATH</fc> particles in the polymer matrix and a synergistic effect between the <fc>DOSA</fc> and <fc>ATH</fc> particles. The char‐formation ability of <fc>EVA</fc> composites has also been analyzed and the synthesized <fc>DOSA</fc> has shown a positive effect. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”XML:ID =“Adv21804-Abs-Ab-0001”> <标题类型=“main”>抽象</ title> > 已经开发出一种含有硅和磷的新的界面改性剂,以改善乙烯 - 乙酸乙酯的阻燃性和机械性能( <FC> EVA </ FC> )/氧化铝三水合物( <FC> ATH </ FC> )复合材料。这 <FC> EVA </ FC> / <FC> ATH </ FC> 通过混合制备复合材料 <FC> EVA </ FC> 不同种类的颗粒 <FC> ATH </ FC> 粒子。结果表明,含磷硅烷偶联剂的协同作用( <FC> DOSA </ FC> ) 和 <FC> ATH </ FC> 颗粒在阻燃性的颗粒 <FC> EVA </ FC> 复合材料。与纯净相比 <FC> EVA </ FC> of 19.1,限制氧指数( <FC> LOI </ FC> )价值增加到31.4。这是形成烧焦层的结果和无机颗粒与聚合物基质之间的增强率。实验结果还表明改进的 <FC> ATH </ FC> 通过合成的颗粒 <FC> DOSA </ FC> 导致机械性能的增加。改善机械和热性能 <FC> EVA </ FC> 复合材料主要归因于修改的更好的分散能力 <FC> ATH </ FC> 聚合物基质中的颗粒和之间的协同效应 <FC> DOSA </ FC> 和 <FC> ATH </ FC> 粒子。炭形成能力 <FC> EVA </ FC> 还分析了复合材料和合成的 <FC> DOSA </ FC> 已经显示出积极的效果。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18410/'>《Advances in Polymer Technology》</a> <b style="margin: 0 2px;">|</b><span>2018年第5期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Bo&option=202" target="_blank" rel="nofollow">Wu Bo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kong Weibo&option=202" target="_blank" rel="nofollow">Kong Weibo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hu Kai&option=202" target="_blank" rel="nofollow">Hu Kai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fu Xiaowei&option=202" target="_blank" rel="nofollow">Fu Xiaowei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lei Jingxin&option=202" target="_blank" rel="nofollow">Lei Jingxin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Changlin&option=202" target="_blank" rel="nofollow">Zhou Changlin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Polymer Materials EngineeringPolymer Research Institute of Sichuan UniversityChengdu China;</p> <p>State Key Laboratory of Polymer Materials EngineeringPolymer Research Institute of Sichuan UniversityChengdu China;</p> <p>State Key Laboratory of Polymer Materials EngineeringPolymer Research Institute of Sichuan UniversityChengdu China;</p> <p>State Key Laboratory of Polymer Materials EngineeringPolymer Research Institute of Sichuan UniversityChengdu China;</p> <p>State Key Laboratory of Polymer Materials EngineeringPolymer Research Institute of Sichuan UniversityChengdu China;</p> <p>State Key Laboratory of Polymer Materials EngineeringPolymer Research Institute of Sichuan UniversityChengdu China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业(高聚物工业)">高分子化合物工业(高聚物工业);</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ethylene‐vinyl acetate&option=203" rel="nofollow">ethylene‐vinyl acetate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=modified&option=203" rel="nofollow">modified;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silane coupling agent&option=203" rel="nofollow">silane coupling agent;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=synergistic flame retardancy&option=203" rel="nofollow">synergistic flame retardancy;</a> </p> <div class="translation"> 机译:乙烯 - 乙酸乙烯酯;改性;硅烷偶联剂;协同阻燃性; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022481734.html">Synergistic effect of phosphorus‐containing silane coupling agent with alumina trihydrate in ethylene‐vinyl acetate composites</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Bo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wu Bo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kong Weibo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kong Weibo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hu Kai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hu Kai,</a> <a href="/journal-foreign-18410/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advances in Polymer Technology .</a> <span>2018</span><span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:含磷硅烷偶联剂与氧化铝三水合物在乙烯 - 乙酸乙烯酯复合材料中的协同作用</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704014520196.html">Flame retardancy and thermal stability of ethylene-vinyl acetate copolymer nanocomposites with alumina trihydrate and montmorillonite</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ming-Kuen Chang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ming-Kuen Chang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shyh-Shin Hwang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shyh-Shin Hwang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sung-Po Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sung-Po Liu </a> <a href="/journal-foreign-34815/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of industrial and engineering chemistry .</a> <span>2014</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:乙烯-乙酸乙烯酯共聚物与三水合氧化铝和蒙脱土的纳米复合材料的阻燃性和热稳定性</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_polymer-degradation-stability_thesis/020419491448.html">Investigation of interfacial modification for flame retardant ethylene vinyl acetate copolymer/alumina trihydrate nanocomposites</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang XG&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang XG,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo F&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guo F,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen JF&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen JF,</a> <a href="/journal-foreign-13742/" target="_blank" rel="nofollow" class="tuijian_authcolor">Polymer Degradation and Stability .</a> <span>2005</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:阻燃乙烯乙酸乙烯酯共聚物/三水合氧化铝纳米复合材料的界面改性研究</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-274632_thesis/0705013475820.html">Effect of silane modification on mechanical and thermal properties of ethylene vinyl acetate (EVA)/zeolite composites</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N. 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tuijian_authcolor">,竺珠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵树高&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵树高</a> <span> <a href="/journal-cn-9131/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成橡胶工业 </a> </span> <span> . 2012</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201293711275.html">成型方法对氢氧化镁/乙烯-乙酸乙烯酯共聚物/线性低密度聚乙烯复合材料结构和热稳定性的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李秀峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李秀峰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐曼&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,徐曼</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢大荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谢大荣</a> <span> <a href="/journal-cn-56862/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子材料科学与工程 </a> </span> <span> . 2010</span><span>,第10期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-22586_thesis/02022661525.html">聚(丙烯腈-乙酸乙烯酯)/黄粘土纳米复合材料研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=祖丽华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 祖丽华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李青山&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李青山</a> <span> <a href="/conference-cn-22586/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第六届功能性纺织品及纳米技术应用研讨会 </a> <span> <span> . 2006</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311605645.html">苯乙烯二聚催化体系的建立及硅烷偶联剂修饰PGS/聚苯乙烯复合材料的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=卢科蓉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 卢科蓉</a> <span> . 2012</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104352724.html">在超临界二氧化碳中制备聚(三氟乙酸乙烯酯)和聚(三氟乙酸乙烯酯/乙烯酯)共聚物的方法</a> <b>[P]</b> . <span> 中国专利: CN1152320A </span> <span> . 1997-06-18</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120104825795.html">乙烯基吡咯烷酮与乙酸乙烯酯的共聚物作为水合物生长抑制剂的应用</a> <b>[P]</b> . <span> 中国专利: CN1635006A </span> <span> . 2005-07-06</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130436638444.html">Multilayer composite comprising chemically-different films with low mutual adhesion and a coupling agent based on ethylene-vinyl acetate copolymer, used for products with good resealing properties, e.g. food packaging</a> <b>[P]</b> . <span> 外国专利: <!-- 德国专利: --> DE102005009664A1 </span> <span> . 2006-09-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:多层复合材料,包括互粘性低的化学差异膜和基于乙烯-乙酸乙烯酯共聚物的偶联剂,用于具有良好密封性能的产品,例如食品包装 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130447883943.html">Intercalates formed by co-intercalation of onium ion spacing/coupling agents and monomer, oligomer or polymer ethylene vinyl alcohol (EVOH) intercalants and nanocomposites prepared with the intercalates</a> <b>[P]</b> . <span> 外国专利: <!-- 美国专利: --> US6225394B1 </span> <span> . 2001-05-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:通过将离子间隔剂/偶联剂与单体,低聚物或聚合物乙烯乙烯醇(EVOH)插层剂以及用该插层制备的纳米复合材料共插层而形成的插层 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130443530239.html">Chopped glass fibres for polyester resin-fibre composite moldings, especially reflecting mirrors for car head lamps, impregnated with a sizing agent containing a urethane resin, a vinyl acetate resin and a coupling agent</a> <b>[P]</b> . <span> 外国专利: <!-- 法国专利: --> FR2831160A1 </span> <span> . 2003-04-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:用于聚酯树脂-纤维复合材料成型件的短切玻璃纤维,尤其是汽车前灯的反射镜,其浸渍有上浆剂,该上浆剂包含聚氨酯树脂,乙酸乙烯酯树脂和偶联剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> </div> <div id="thesis_get_original1" 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