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首页> 外文期刊>Advances in Polymer Technology >The relationship of vulcanization and structural characteristics‐dispersion of organoclay‐mechanical properties in?(butadiene rubber/natural rubber) based nanocomposite
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The relationship of vulcanization and structural characteristics‐dispersion of organoclay‐mechanical properties in?(butadiene rubber/natural rubber) based nanocomposite

机译：有机粘土机械性能硫化和结构特征 - 分散在α（丁二烯橡胶/天然橡胶）的纳米复合材料的关系

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Abstract > Nanocomposites based on (organoclay [ <fc>OC</fc> ]/butadiene rubber [ <fc>BR</fc> ]/natural rubber [ <fc>NR</fc> ]) containing different ratio of (sulfur/accelerator [dibenzothiazyl disulfide ( <fc>MBTS</fc> )] or N ‐Oxydiethyl‐2‐benzthiazolsulfenamid ( <fc>NOBS</fc> )) were prepared. Evaluation of the vulcanization characteristics showed that the curing system and the type of the used accelerator affected the impact of the <fc>OC</fc> on the scorch and cure times. The crosslink density and the percentage of polysulfide bonds of the compounds were enhanced by using <fc>OC</fc> . X‐ray diffraction ( <fc>XRD</fc> ) analysis showed that the type of curing system and the used accelerator affected the network structure as well as the expansion of the interlayer space of the <fc>OC</fc> . In nanocomposites with less crosslink density and less polysulfide bonds, greater expansion of the <fc>OC</fc> interlayer spaces was observed. The use of the <fc>OC</fc> and its effect on the level of crosslink density and percent of polysulfide bonds affected the tensile properties and abrasion loss of the samples. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract xmlns =“http://www.wiley.com/namespaces/wiley”type =“main”XML：ID =“Adv21805-Abs-0001”> <标题类型=“main”>抽象</ title> > 纳米复合材料基于（Organoclay [ <FC> OC </ FC> ] /丁二烯橡胶[ <FC> BR </ FC> ]/天然橡胶 [ <FC> NR </ FC> ]）含有不同的（硫/促进剂[二苯甲酸噻嗪二硫化物（ <FC> MBTS </ FC> ）] 或者 n </ i> -Oxydiethyl-2-苯并噻唑氟苯胺（ <FC> NOBS </ FC> ））制备。硫化特征的评价表明，固化系统和使用的促进剂的类型影响了影响的影响 <FC> OC </ FC> 在烧焦和治疗时代。通过使用增强了化合物的交联密度和聚硫化物键的百分比 <FC> OC </ FC> 。 X射线衍射 （ <FC> XRD </ FC> ）分析表明，固化系统的类型和二手加速器影响了网络结构以及延伸了层间空间的膨胀 <FC> OC </ FC> 。在纳米复合材料中具有较少的交联密度和较少的多硫化物键，较大的膨胀 <FC> OC </ FC> 观察到层间空间。使用 <FC> OC </ FC> 其对交联密度水平和多硫化物键百分比的影响影响了样品的拉伸性能和磨损损失。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18410/'>《Advances in Polymer Technology》</a> <b style="margin: 0 2px;">|</b><span>2018年第5期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zarei Ahmad&option=202" target="_blank" rel="nofollow">Zarei Ahmad;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jalali‐Arani Azam&option=202" target="_blank" rel="nofollow">Jalali‐Arani Azam;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Mahshahr CampusAmirkabir University of TechnologyMahshahr Iran;</p> <p>Department of Polymer Engineering &</p> <p>Color TechnologyAmirkabir University of TechnologyTehran Iran;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业（高聚物工业）">高分子化合物工业（高聚物工业）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanical properties&option=203" rel="nofollow">mechanical properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanocomposites&option=203" rel="nofollow">nanocomposites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organoclay&option=203" rel="nofollow">organoclay;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rubber&option=203" rel="nofollow">rubber;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=vulcanization&option=203" rel="nofollow">vulcanization;</a> </p> <div class="translation"> 机译：机械性能;纳米复合材料;有机粘土;橡胶;硫化; 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Maria,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martin George Thomas&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Martin George Thomas,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Marco Morreale&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Marco Morreale,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：不混溶的天然橡胶/丙烯腈-丁二烯橡胶/有机粘土（NR / NBR /有机粘土）共混纳米复合材料的阻气性流变学和力学性能</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000124542773.html">Enhancement of mechanical properties of natural rubber–clay nanocomposites through incorporation of silanated organoclay into natural rubber latex</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sudarshana Jayaraj Perera&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sudarshana Jayaraj Perera,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shantha Maduwage Egodage&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shantha Maduwage Egodage,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shantha Walpalage&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shantha Walpalage </a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过将硅烷化有机粘土掺入天然橡胶胶乳中的天然橡胶粘土纳米复合材料的力学性能</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_rubber-reference-material_thesis/0201251916901.html">天然橡胶／有机粘土纳米复合材料的制备与表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邱一夔&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 邱一夔</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王韶晖&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王韶晖</a> <span> <a href="/journal-cn-9035/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 橡胶参考资料 </a> </span> <span> . 2004</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_china-rubber-industry_thesis/0201280188601.html">有机粘土/丁基橡胶和有机粘土/氯化丁基橡胶纳米复合材料的结构与性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=龙伦&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 龙伦</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=梁玉蓉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,梁玉蓉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王林艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王林艳</a> <span> <a href="/journal-cn-9238/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 橡胶工业 </a> </span> <span> . 2020</span><span>,第008期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_world-rubber-industry_thesis/02012188449.html">用尼龙短纤维增强的天然橡胶/再生橡胶并用胶的物理机械性能和硫化特性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陶华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陶华</a> <span> <a href="/journal-cn-9270/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 世界橡胶工业 </a> </span> <span> . 2005</span><span>,第007期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_rubber-reference-material_thesis/0201251940190.html">炭黑填充的丁苯橡胶和环氧化天然橡胶共混胶的硫化特性和机械性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=NasirM&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . NasirM</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李九玉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李九玉</a> <span> <a href="/journal-cn-9035/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 橡胶参考资料 </a> </span> <span> . 1990</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_rubber-reference-material_thesis/0201271033925.html">天然橡胶和聚丁二烯橡胶不同硫化体系对老化硬化和疲劳裂纹扩展特性影响的对比研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杜娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杜娟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙海英&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,孙海英</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔国成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,崔国成</a> <span> <a href="/journal-cn-9035/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 橡胶参考资料 </a> </span> <span> . 2018</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-26770_thesis/020221700395.html">马来酸酐化聚丁二烯（MLPB）对天然橡胶硫化胶抗撕裂性能的影响</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱闰平&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱闰平</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨军</a> <span> <a href="/conference-cn-26770/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2005年全国高分子学术论文报告会 </a> <span> <span> . 2005</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315882695.html">结晶型橡胶/有机粘土纳米复合材料拉伸诱导结晶行为的影响</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=崔海波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 崔海波</a> <span> . 2020</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104017602.html">硫改性氯丁二烯橡胶组合物及硫化物、以及使用该硫化物的成型品及硫改性氯丁二烯橡胶组合物的制造方法</a> <b>[P]</b> . <span> 中国专利： CN111372986A </span> <span> . 2020-07-03</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061204481511.html">一种耐老化天然橡胶及其制备方法、耐老化天然橡胶硫化胶及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN110511454B </span> <span> . 2021.06.22</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130499663798.html">Process for producing acrylonitrile-butadiene-styrene (ABS) powder based on natural rubber, process for producing acrylonitrile-butadiene-styrene (ABS) product based on natural rubber and acrylonitrile-butadiene-styrene (ABS) powder based on natural rubber</a> <b>[P]</b> . <span> 外国专利： <!-- --> DE112011100053B4 </span> <span> . 2021-03-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于天然橡胶的基于天然橡胶的丙烯腈 - 丁二烯 - 苯乙烯（ABS）粉末的方法，基于天然橡胶的天然橡胶和丙烯腈 - 丁二烯 - 苯乙烯（ABS）粉末的丙烯腈 - 丁二烯 - 苯乙烯（ABS）产物的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130500875358.html">Process for producing acrylonitrile-butadiene-styrene (ABS) powder based on natural rubber, process for producing acrylonitrile-butadiene-styrene (ABS) product based on natural rubber and acrylonitrile-butadiene-styrene (ABS) powder based on natural rubber</a> <b>[P]</b> . <span> 外国专利： <!-- --> DE112011100053B9 </span> <span> . 2021-10-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于天然橡胶的天然橡胶制备丙烯腈 - 丁二烯 - 苯乙烯（ABS）粉末的方法，基于天然橡胶和丙烯腈 - 丁二烯 - 苯乙烯（ABS）粉末的丙烯腈 - 丁二烯 - 苯乙烯（ABS）产物为基于天然橡胶的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130484996285.html">METHOD OF REGENERATION OF RUBBER1 This invention relates to methods for regenerating rubber based on butyl rubber, vulcanized with resins, using activators. Methods are known to regenerate vulcanized butyl rubber using activators, for example, alkylphenol disulfide, halogen-containing patterns, and body patterns and aromatics and aromatics with the use of activators; as well as improving the quality of the regenerate, it is proposed to use as an activator in the regeneration of butyl rubber, vulcanized with resins, diphenylguanium Din. The method consists in the following. To 100 weight. Part of waste or rejected rubber based on butyl rubber, vulcanized with resins, previously crushed on the crushing rollers, add 2-4 weight. including activator of destruction - diphenylguanidine known method. The mixture is heated in an air or vapor-air environment at a temperature of 160-180 ° C for 2-3 hours. After heating, the devulcanized product is subjected to additional mechanical treatment to h</a> <b>[P]</b> . <span> 外国专利： <!-- --> SU433165A1 </span> <span> . 1974-06-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：橡胶的再生方法本发明涉及使用活化剂再生基于丁基橡胶的橡胶的方法，该丁基橡胶经树脂硫化。已知使用活化剂来再生硫化丁基橡胶的方法，所述活化剂例如为烷基酚二硫化物，含卤素的图案和主体图案以及使用活化剂的芳族化合物和芳族化合物。除了提高再生物的质量外，还建议将其用作丁基橡胶再生中的活化剂，该丁基橡胶经树脂硫化二苯基胍丁。该方法包括以下内容。达到100重量。废树脂或废旧丁基橡胶制的一部分，用树脂硫化，事先在破碎辊上破碎，再增加2-4重量。包括破坏活化剂-二苯基胍的已知方法。将混合物在空气或蒸气-空气环境中在160-180°C的温度下加热2-3小时。加热后，将脱硫产品进行额外的机械处理至 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" 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