A Facile and Controllable Method to In Situ Synthesize Stable Hydrophobic Vaterite Particles

Dang Haichun; Xu Zhaozan; Chen Zishan; Wu Weiling; Feng Juan; Sun Yiyi; Jin Fengchi; Li Jiang; Ge Fan

摘要

Abstract > The applications of hydrophobic vaterite in various fields have been limited by its thermodynamic instability and complex preparation methods. A facile batch, green, rapid, and controllable method is proposed to prepare stable hydrophobic vaterite microparticles with the presence of stearic acid (SA) via in situ synthesis. A possible formation process of SA‐modified calcium carbonate (CaCO <sub>3</sub> ) particles is proposed. Hydrophobic vaterite is prepared by mixing calcium chloride and sodium carbonate aqueous solutions in the presence of SA within 1?min by high shearing stirring. The hydrophobic vaterite particles show more uniform morphology and particle size than that without SA. Interestingly, the hydrophobic vaterite particles exhibit sumac‐fruit‐like morphology consisting of spherical nanoparticles. The hydrophobicity of CaCO <sub>3</sub> particles is enhanced significantly by 1% SA addition. Vaterite is stabilized by SA and vaterite content in CaCO <sub>3</sub> particles is significantly enhanced from 35% to 97% based on the analysis of X‐ray diffraction data. CaCO <sub>3</sub> particles without SA translate into rhombohedron completely after 24 h of incubation, while the sumac‐fruit‐like morphology of hydrophobic vaterite particles shows no obvious change after 96 h of incubation. No obvious phase transformation of the hydrophobic vaterite particles is found after 72 h of incubation, indicating high stability of the hydrophobic vaterite. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</ title> >疏水性Vaterite在各种领域的应用受到其热力学不稳定和复杂的制备方法的限制。提出了一种容易批次，绿色，快速和可控方法，以通过原位合成在存在硬脂酸（SA）的情况下制备稳定的疏水性Vaterite微粒。提出了SA改性碳酸钙（Caco <Sub> 3 </ sub>）颗粒的可能形成过程。通过高剪切搅拌将氯化钙和碳酸钙水溶液混合在1℃内，通过高剪切搅拌将碳酸钙和碳酸钠水溶液混合来制备。疏水性Vaterite颗粒显示出比没有SA的没有SA更均匀的形态和粒径。有趣的是，疏水性Vaterite颗粒表现出由球形纳米颗粒组成的Sumac果实形态。 CaCO <sub> 3 </ sub>颗粒的疏水性显着增强1％SA添加。 Vaterite通过SA通过SA稳定，Caco <sub> 3 </ sub>颗粒中的Vaterite含量根据X射线衍射数据的分析显着增强35％至97％。 Caco <sub> 3 </ sub>颗粒没有SA完全在孵育24小时后完全转化为菱体，而疏水性Vaterite颗粒的SuMac-果实形态显示出96小时后没有明显的变化。孵育72小时后发现疏水性Vaterite颗粒的明显相变，表明疏水性Vaterite的高稳定性。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18164/'>《Crystal Research and Technology: Journal of Experimental and Industrial Crystallography》</a> <b style="margin: 0 2px;">|</b><span>2019年第5期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dang Haichun&option=202" target="_blank" rel="nofollow">Dang Haichun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xu Zhaozan&option=202" target="_blank" rel="nofollow">Xu Zhaozan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Zishan&option=202" target="_blank" rel="nofollow">Chen Zishan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Weiling&option=202" target="_blank" rel="nofollow">Wu Weiling;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Feng Juan&option=202" target="_blank" rel="nofollow">Feng Juan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Yiyi&option=202" target="_blank" rel="nofollow">Sun Yiyi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jin Fengchi&option=202" target="_blank" rel="nofollow">Jin Fengchi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Jiang&option=202" target="_blank" rel="nofollow">Li Jiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ge Fan&option=202" target="_blank" rel="nofollow">Ge Fan;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Shanxi Collaborative Innovation Center of High Value‐Added Utilization of Coal‐Related WastesShanxi UniversityTaiyuan 030006 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> <p>Department of Materials EngineeringTaiyuan Institute of TechnologyTaiyuan 030008 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/160.html" title="晶体学">晶体学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrophobicity&option=203" rel="nofollow">hydrophobicity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=in situ&option=203" rel="nofollow">in situ;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=stability&option=203" rel="nofollow">stability;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=stearic acid&option=203" rel="nofollow">stearic acid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=vaterite&option=203" rel="nofollow">vaterite;</a> </p> <div class="translation"> 机译：疏水性;原位;稳定性;硬脂酸;Vaterite; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022450854.html">A Facile and Controllable Method to In Situ Synthesize Stable Hydrophobic Vaterite Particles</a> <b>[J]</b> . <span> <a 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