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Elucidating the Mechanism Involved in the Performance Improvement of Lithium‐Ion Transition Metal Oxide Battery by Conducting Polymer

机译:通过导电聚合物阐明锂离子过渡金属氧化物电池性能改善的机制

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Abstract >Surface treatments with conducting polymers are effective in ameliorating charge capacities and cycling performances for a wide range of lithium‐ion batteries such as Li‐layered transition metal oxide, Li‐sulfur, and Li‐air batteries. So far, however, very little is known about the key process directly involved with the improvement of cell performance and stability. The present study examines how a conducting polymer can contribute to charge capacity enhancement, employing poly(3,4‐ethylenedioxythiophene):poly(styrene‐sulfonate) coating on the lithium‐layered transition metal oxide cathode. The property of the electrode interface layer is studied on the basis of the local atomic environments. The conducting polymer not only hinders the formation of LiF, carbonates, and semicarbonates compounds but also renders the nature of the solid‐electrolyte interphase layer formed during electrochemical cycles. Furthermore, it inhibits the dissolution of the active material into the electrolyte and preserves the initial atomic states including the active material bulk. The coating enables good consistency in the local atomic environment with depth at the electrode interface, which in turn impedes the phase mismatch resulting from the surface reconstruction on the layered oxide electrode. This further mitigates the phase transformation of the active material, resulting in a lower voltage decay on charge–discharge. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> 具有导电聚合物的表面处理在改善电荷容量和循环性能的各种锂离子电池中是有效的,例如Li叠层过渡金属氧化物,Li-硫和Li-Air电池。然而,到目前为止,关于直接涉及细胞性能和稳定性的关键过程很少。本研究研究了导电聚合物如何有助于充电能力增强,采用聚(3,4-亚乙基二氧噻吩):聚(苯乙烯 - 磺酸盐)涂层在锂层的过渡金属氧化物阴极上。基于局部原子环境研究电极接口层的性质。导电聚合物不仅阻碍了LiF,碳酸盐和碳酸齐氢化合物的形成,而且还使电化学循环期间形成的固体电解质相互相位层的性质。此外,它抑制活性物质溶解到电解质中,并保留包括活性物质体积的初始原子状态。涂层能够在局部原子环境中具有良好的一致性,在电极接口处具有深度,这反过来阻碍由层状氧化物电极上的表面重建产生的相位错配。这进一步减轻了活性材料的相变,导致充电放电的较低电压衰减。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2019年第7期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kim Taehoon&option=202" target="_blank" rel="nofollow">Kim Taehoon;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ono Luis K.&option=202" target="_blank" rel="nofollow">Ono Luis K.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qi Yabing&option=202" target="_blank" rel="nofollow">Qi Yabing;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Energy Materials and Surface Sciences Unit (EMSSU)Okinawa Institute of Science and Technology Graduate University (OIST)1919‐1 Tancha Onna‐son Okinawa 904‐0495 Japan;</p> <p>Energy Materials and Surface Sciences Unit (EMSSU)Okinawa Institute of Science and Technology Graduate University (OIST)1919‐1 Tancha Onna‐son Okinawa 904‐0495 Japan;</p> <p>Energy Materials and Surface Sciences Unit (EMSSU)Okinawa Institute of Science and Technology Graduate University (OIST)1919‐1 Tancha Onna‐son Okinawa 904‐0495 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=conducting polymers&option=203" rel="nofollow">conducting polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium‐ion batteries&option=203" rel="nofollow">lithium‐ion batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mitigating phase mismatches&option=203" rel="nofollow">mitigating phase mismatches;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=PEDOT&option=203" rel="nofollow">PEDOT;</a> </p> <div class="translation"> 机译:导电聚合物;锂离子电池;减轻相位错配;转型; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋怀河&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋怀河</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈晓红&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈晓红</a> <span> <a href="/conference-cn-15571/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第三届中国储能与动力电池及其关键材料学术研讨与技术交流会 </a> <span> <span> . 2009</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311322861.html">过渡金属氧化物和过渡金属硫化物作为锂离子电池负极材料的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王会军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王会军</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061202553229.html">锂‑过渡金属氧化物粉体及其制造方法、锂离子电池用正极活性物质、以及锂离子二次电池</a> <b>[P]</b> . <span> 中国专利: CN103124695B </span> <span> . 2017.08.15</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120109771710.html">过渡金属氧化物/石墨烯复合材料的制备方法、锂离子电池负极、锂离子电池</a> <b>[P]</b> . <span> 中国专利: CN107293710A </span> <span> . 2017-10-24</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130500848027.html">Lithium transition metal composite oxide, transition metal hydroxide precursor, method for producing transition metal hydroxide precursor, method for producing lithium transition metal composite oxide, positive active material for nonaqueous electrolyte secondary battery, electrode for nonaqueous electrolyte secondary battery, nonaqueous electrolyte secondary battery and energy storage apparatus</a> <b>[P]</b> . <span> 外国专利: <!-- --> US11152616B2 </span> <span> . 2021-10-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:锂过渡金属复合氧化物,过渡金属氢氧化物前体,生产过渡金属氢氧化物前体的方法,生产锂过渡金属复合氧化物的方法,非水电解质二次电池阳性活性材料,非水电解质二次电池电极,非水电解质二次电池和能量 存储装置 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130404202555.html">LITHIUM TRANSITION METAL COMPOSITE OXIDE, TRANSITION METAL HYDROXIDE PRECURSOR, METHOD FOR PRODUCING TRANSITION METAL HYDROXIDE PRECURSOR, METHOD FOR PRODUCING LITHIUM TRANSITION METAL COMPOSITE OXIDE, POSITIVE ACTIVE MATERIAL FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY, ELECTRODE FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY, NONAQUEOUS ELECTROLYTE SECONDARY BATTERY AND ENERGY STORAGE APPARATUS</a> <b>[P]</b> . <span> 外国专利: <!-- 美国专利: --> US2019341609A1 </span> <span> . 2019-11-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:过渡金属锂复合氧化物,过渡金属氢氧化物前体,过渡金属氢氧化物前体的制备方法,过渡金属氢氧化锂复合物的制备方法,电极间介电质子线,电极间的正电活性材料,电极间介电常数,电极储存装置 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130404797908.html">Lithium transition metal composite oxide, transition metal hydroxide precursor, method of producing transition metal hydroxide precursor, method of producing lithium transition metal composite oxide, positive electrode active material for non-aqueous electrolyte secondary battery, non-aqueous electrolyte Electrode for secondary battery, non-aqueous electrolyte secondary battery and storage device</a> <b>[P]</b> . <span> 外国专利: <!-- 日本专利: --> JPWO2018012384A1 </span> <span> . 2019-05-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> 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