Boosting Hydrogen Evolution Performance of MoS ₂2 by Band Structure Engineering

摘要

> Molybdenum sulfide (MoS ₂ ) has emerged as a promising electrocatalyst for hydrogen evolution reaction (HER) owing to its high activity and stability during the reaction. However, the efficiency of hydrogen production is limited by the number of active sites in MoS ₂ . In this work, a simple method of fabricating polycrystalline multilayer MoS ₂ on Mo foil for efficient hydrogen evolution is demonstrated by controlling the sulfur (S) vacancy concentration, which can introduce new bands and lower the hydrogen adsorption free energy (Δ G _H ). For the first time, theoretical and experimental results show that the HER performance of synthesized MoS ₂ with S vacancy can be further enhanced by the very small amount of platinum (Pt) decoration, which can introduce new gap states and more catalytic sites in real space with suitable free energy. The fabricated hybrid electrocatalyst exhibits significantly smaller Tafel slope of 38 mV dec ?1 and better HER electrocatalytic activity compared to previous works. This approach provides a simple pathway to design low‐cost, efficient and sizable hydrogen‐evolving electrode by simultaneously tuning the MoS ₂ band structure and active sites.