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Self‐Tuning n‐Type Bi 22 (Te,Se) 33 /SiC Thermoelectric Nanocomposites to Realize High Performances up to 300 °C

机译:自调整n型BI 2 2 (te,se) 3 3 / SiC热电纳米复合材料,实现高达300°C的高性能

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Abstract > Bi <sub>2</sub> Te <sub>3</sub> thermoelectric materials are utilized for refrigeration for decades, while their application of energy harvesting requires stable thermoelectric and mechanical performances at elevated temperatures. This work reveals that a steady zT of ≈0.85 at 200 to 300 °C can be achieved by doping small amounts of copper iodide (CuI) in Bi <sub>2</sub> Te <sub>2.2</sub> Se <sub>0.8</sub> –silicon carbide (SiC) composites, where SiC nanodispersion enhances the flexural strength. It is found that CuI plays two important roles with atomic Cu/I dopants and CuI precipitates. The Cu/I dopants show a self‐tuning behavior due to increasing solubility with increasing temperatures. The increased doping concentration increases electrical conductivity at high temperatures and effectively suppresses the intrinsic excitation. In addition, a large reduction of lattice thermal conductivity is achieved due to the “in situ” CuI nanoprecipitates acting as phonon‐scattering centers. Over 60% reduction of bipolar thermal conductivity is achieved, raising the maximum useful temperature of Bi <sub>2</sub> Te <sub>3</sub> for substantially higher efficiency. For module applications, the reported materials are suitable for segmentation with a conventional ingot. This leads to high device ZT values of ≈0.9–1.0 and high efficiency up to 9.2% from 300 to 573 K, which can be of great significance for power generation from waste heat. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml:lang =“en”> <标题类型=“main”>抽象</ title> > 双 <sub> 2 </ sub> te. <sub> 3 </ sub> 热电材料用于几十年的制冷,而它们的能量收集的应用需要在升高的温度下稳定的热电和机械性能。这项工作揭示了一个稳定的 zt </ i> 通过掺杂BI中的少量铜碘化物(CUI),可以实现200至300℃的≈0.85。 <sub> 2 </ sub> te. <sub> 2.2 </ sub> se <sub> 0.8 </ sub> - 碳化硅(SiC)复合材料,其中SiC纳米分散可增强弯曲强度。结果发现崔在原子Cu / I掺杂剂和崔沉淀物中起两个重要的作用。 Cu / I掺杂剂由于随着温度的增加而增加,由于增加的溶解度增加,因此具有自调谐行为。增加的掺杂浓度增加了高温下的电导率,并有效地抑制了内在激发。此外,由于作为声子散射中心的“原位”Cui Nanoplecitate,因此实现了大的晶格导热率的大量减少。实现了双极导热率超过60%,提高了BI的最大有用温度 <sub> 2 </ sub> te. <sub> 3 </ sub> 为了大大更高的效率。对于模块应用,报告的材料适用于常规锭的分段。这导致高设备 zt </ i> 值≈0.9-1.0,高效率高达300至573 k,这对废热的发电具有重要意义。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces 》</a> <b style="margin: 0 2px;">|</b><span>2017年第11期</span><b style="margin: 0 2px;">|</b> <span>共1页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pan Yu&option=202" target="_blank" rel="nofollow">Pan Yu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aydemir Umut&option=202" target="_blank" rel="nofollow">Aydemir Umut;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Fu‐Hua&option=202" target="_blank" rel="nofollow">Sun Fu‐Hua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Chao‐Feng&option=202" target="_blank" rel="nofollow">Wu Chao‐Feng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chasapis Thomas C.&option=202" target="_blank" rel="nofollow">Chasapis Thomas C.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Snyder G. Jeffrey&option=202" target="_blank" rel="nofollow">Snyder G. Jeffrey;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Jing‐Feng&option=202" target="_blank" rel="nofollow">Li Jing‐Feng;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of New Ceramics and Fine ProcessingTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Department of Materials Science and EngineeringNorthwestern UniversityEvanston IL 60208 USA;</p> <p>State Key Laboratory of New Ceramics and Fine ProcessingTsinghua UniversityBeijing 100084 P. R. China;</p> <p>State Key Laboratory of New Ceramics and Fine ProcessingTsinghua UniversityBeijing 100084 P. R. China;</p> <p>Department of Materials Science and EngineeringNorthwestern UniversityEvanston IL 60208 USA;</p> <p>Department of Materials Science and EngineeringNorthwestern UniversityEvanston IL 60208 USA;</p> <p>State Key Laboratory of New Ceramics and Fine ProcessingTsinghua UniversityBeijing 100084 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bismuth‐telluride‐selenide&option=203" rel="nofollow">bismuth‐telluride‐selenide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=device figure of merit&option=203" rel="nofollow">device figure of merit;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=self‐tuning&option=203" rel="nofollow">self‐tuning;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thermoelectrics&option=203" rel="nofollow">thermoelectrics;</a> </p> <div class="translation"> 机译:铋 - 碲化物 - 硒化物;器件的优点;自调整;热电; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022435325.html">Self‐Tuning n‐Type Bi <sub xmlns="http://www.wiley.com/namespaces/wiley">2</sub>2 (Te,Se) <sub xmlns="http://www.wiley.com/namespaces/wiley">3</sub>3 /SiC Thermoelectric Nanocomposites to Realize High Performances up to 300 °C</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pan Yu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Pan Yu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aydemir Umut&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Aydemir Umut,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Fu‐Hua&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sun Fu‐Hua,</a> <a href="/journal-foreign-18063/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced materials interfaces .</a> <span>2017</span> <span>,第11期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:自调整n型BI <sub xmlns =“http://www.wiley.com/namespaces/wiley”> 2 </ sub> 2 (te,se) <sub xmlns =“http://www.wiley.com/namespaces/wiley”> 3 </ sub> 3 / SiC热电纳米复合材料,实现高达300°C的高性能</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020203489.html">Abnormal polar nanoregion evolution in (Bi <sub xmlns="http://www.wiley.com/namespaces/wiley">0.09</sub>0.09 Ba <sub xmlns="http://www.wiley.com/namespaces/wiley">0.91</sub>0.91 )(Zn <sub xmlns="http://www.wiley.com/namespaces/wiley">0.045</sub>0.045 Ti <sub xmlns="http://www.wiley.com/namespaces/wiley">0.955</sub>0.955 )O <sub xmlns="http://www.wiley.com/namespaces/wiley">3</sub>3 (9BZT‐BT) ceramic</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shi Jing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shi Jing,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cui Naiyuan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Cui Naiyuan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiaoli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Xiaoli,</a> <a href="/journal-foreign-29289/" target="_blank" rel="nofollow" class="tuijian_authcolor">Physica status solidi, B. 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