Removal of Conflicting Molecular Symmetries Restores a Hexagonal Array of Six-Fold Phenyl Embraces in a bis(Trityl)-Containing Compound.I.Crystals of l,l,l,6,6,6-Hexaphenyl-2,4-hexadiyne

摘要

Previously reported structures of 1,4-bis(3,3,3-triphenylpropynyl)benzene (1) showed molecules adopting a C_i point group in the triclinic space group P1.Reasoning that a symmetry conflict between the 3-fold symmetric triphenylmethyl groups and the 2-fold symmetric phenyl group may be responsible for the low symmetry crystal structure,it was speculated that the removal of the central benzene ring might lead to crystal symmetries where the molecular 3-fold axes might be elicited.To test that,we analyzed the crystallization and packing of 1,1,1,6,6,6-hexaphenyl-2,4-hexadiyne (2).Satisfyingly,compound 2 was found to crystallize in the rhombohedral space group R3 with three different molecular structures,one displaying a chiral C_3 point group and the others a meso conformation with an S_6 point group.