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Highly accurate transport properties of helium-4, helium-3, and their binary mixtures by ab initio potential

机译:从头算势出发对He-4,He-3及其二元混合物的高精度传输性质

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摘要

A helium-helium interatomic potential determined from quantum-mechanical ab initio calculations by Przybytek et al. has been used in the framework of the classical kinetic theory to calculate the transport properties of helium. The viscosity, thermal conductivity, diffusion coefficient, and thermal diffusion factor were calculated for helium-4, helium-3, and their binary mixtures at low density between 100 and 10,000 K. The predicted results of this work are listed in the Appendix, which are more accurate than the corresponding measured quantities over a wide temperature range.
机译:Przybytek等人通过量子力学从头算确定的氦-氦原子间电势。已在经典动力学理论的框架内使用He来计算氦的传输性质。计算了100至10,000 K之间低密度的He-4,He-3及其二元混合物的粘度,导热系数,扩散系数和热扩散系数。该工作的预测结果列在附录中,该附录在较宽的温度范围内比相应的测量量更精确。

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