Chitosan derivatives as green corrosion inhibitors for P110 steel in a carbon dioxide environment

摘要

Two chitosan derivatives were synthesized for the first time as green corrosion inhibitors for the carbon dioxide corrosion of P110 steel. The structures of the synthesized products were characterized by infrared spectroscopy. Electrochemical and weight-loss experiments were used to test the effect of corrosion inhibitors, while SEM-EDS, AFM and other analysis methods were used to study the protection mechanism of corrosion inhibitors. The experimental results show that synthetic corrosion inhibitors CHC and CAHC are all good corrosion inhibitors for carbon dioxide corrosion inhibition. Both chitosan derivatives can form hydrophobic protective films on the metal surface. For inhibition performance, CAHC is better than CHC, which is the same conclusion drawn from practical experiments and quantum chemical calculations. Investigation into chitosan inhibitors has opened up a new area of research of environmentally friendly corrosion inhibitors, which is of great significance for metal protection without toxicity and side effects.