Flexible Metal–Porphyrin Dimers (M=Mn III III Cl, Co II II , Ni II II , Cu II II ): Synthesis, Spectroscopy, Electrochemistry, Spectroelectrochemistry, and Theoretical Calculations

Li Minzhi; Zhang Qian; Xu Li; Zhu Weihua; Mack John; May Aviwe K.; Nyokong Tebello; Kobayashi Nagao; Liang Xu

首页> 外文期刊>ChemPlusChem >Flexible Metal–Porphyrin Dimers (M=Mn III III Cl, Co II II , Ni II II , Cu II II ): Synthesis, Spectroscopy, Electrochemistry, Spectroelectrochemistry, and Theoretical Calculations

【24h】

Flexible Metal–Porphyrin Dimers (M=Mn III III Cl, Co II II , Ni II II , Cu II II ): Synthesis, Spectroscopy, Electrochemistry, Spectroelectrochemistry, and Theoretical Calculations

机译：柔性金属 - 卟啉二聚体（M = Mn III III Cl，CO II II，Ni II II，Cu II II）：合成，光谱，电化学，光谱电化学和理论计算

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract Four metalloporphyrin dimers linked by bridging amide‐bonded xanthene moieties and that contain either Mn III , Co II , Ni II , or Cu II metal centers were synthesized. Various spectroscopic, electrochemical, and spectroelectrochemical methods were used to study trends in their properties. Their electronic structure and optical properties were analyzed through a comparison of the electronic absorption and magnetic circular dichroism (MCD) spectral data with the results of time‐dependent (TD)‐DFT calculations.

机译：摘要通过桥接酰胺键合的X吨部分和含有Mn III，CO II，Ni II或Cu II金属中心连接的四个金属卟啉二聚体。各种光谱，电化学和光谱电化学方法用于研究其性质的趋势。通过比较电子吸收和磁性圆形二色（MCD）光谱数据与时间依赖性（TD）-DFT计算结果进行分析它们的电子结构和光学性质。

著录项

来源
《ChemPlusChem》 |2017年第4期|共9页
作者
Li Minzhi; Zhang Qian; Xu Li; Zhu Weihua; Mack John; May Aviwe K.; Nyokong Tebello; Kobayashi Nagao; Liang Xu;
展开▼
作者单位

School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013 P. R. China;

School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013 P. R. China;

School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013 P. R. China;

School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013 P. R. China;

Department of ChemistryRhodes UniversityGrahamstown 6140 South Africa;

Department of ChemistryRhodes UniversityGrahamstown 6140 South Africa;

Department of ChemistryRhodes UniversityGrahamstown 6140 South Africa;

Faculty of Textile Science and TechnologyShinshu UniversityUeda 386-8567 Japan;

School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013 P. R. China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
amides; density functional calculations; electrochemistry; heterocycles; porphyrinoids;

机译：酰胺;密度函数计算;电化学;杂环;卟啉曲线;

相似文献

外文文献
中文文献
专利

1. Synthesis, Crystal Structure and Fluorescent Property of d-f Heterodinuclear Eu(III)-M(II) (M=Cd(II), Ni(II)) Cryptates. [J] . 中国化学快报（英文版） . 2002,第008期
2. Flexible Metal–Porphyrin Dimers (M=Mn III III Cl, Co II II , Ni II II , Cu II II ): Synthesis, Spectroscopy, Electrochemistry, Spectroelectrochemistry, and Theoretical Calculations [J] . Li Minzhi, Zhang Qian, Xu Li, ChemPlusChem . 2017,第4期

机译：柔性金属 - 卟啉二聚体（M = Mn III III Cl，CO II II，Ni II II，Cu II II）：合成，光谱，电化学，光谱电化学和理论计算
3. Encapsulation by a chromium(III)-containing bicyclic ligand cage. Synthesis, structures, and physical properties of heterometal complexes Cr-III MCrIII [M=(H+)(2), Li(I), Mg(II), Cu(II), Ni(II), Ni(IV), Co(III), Fe(II), Fe(III), Mn(II)] [J] . Burdinski D., Weyhermuller T., Florke U., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第5期

机译：通过含铬（III）的双环配体笼进行封装。杂金属配合物Cr-III MCrIII [M =（H +）（2），Li（I），Mg（II），Cu（II），Ni（II），Ni（IV），Co的合成，结构和物理性质（III），Fe（II），Fe（III），Mn（II）]
4. Synthesis, electrochemistry and In situ spectroelectrochemistry of novel tetra dimethyl 5-oxyisophthalate substituted Co(II), Mn(III), and mu-oxo-dimer Fe(III) phthalocyanines [J] . Koksoy Baybars, Soyer Oksan, Orman Efe Baturhan, Dyes and Pigments . 2015,第Null期

机译：新型5-氧间苯二甲酸四甲基二甲酯取代的Co（II），Mn（III）和多氧二聚体Fe（III）酞菁的合成，电化学和原位光谱电化学
5. Heteropolynuclear Complex Precursors Used in M(III)M(II)_2Cu_3O_(7-delta) Mixed Oxides Synthesis (M(III)=La, Ce, Y; M(II)=Sr, Ba) [C] . C. Guran, I. Jitaru, E. Andronescu, Conference and exhibition of the European ceramic society;ECerS-V . 1997

机译：用于M（III）M（II）_2Cu_3O_（7-δ）混合氧化物合成的杂多核络合物前体（M（III）= La，Ce，Y; M（II）= Sr，Ba）
6. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

机译：Ru和Mn的一系列高价羰基配合物的结构和反应性：Ru（III）介导的三苯膦催化氧化，双核Mn（III，III）和Mn（III，IV）二聚体的表征以及单核铁（III）和铁（IV）。
7. Cyclometalated Ir(III) Complex as a Metalloligandand a Selective Cu(II) Sensor: Synthesis and Structural Characterizationof a Heterometallic Tetranuclear Ir(III)/Cu(II) Complex [O] . Vadapalli Chandrasekhar, *, Bani Mahanti, 2018

机译：金属配体的环金属化Ir（III）配合物和选择性Cu（II）传感器：合成与结构表征金属四核Ir（III）/ Cu（II）配合物的合成
8. Synthesis and characterization of metal complexes of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Ru(III), Rh(III) and Pd(II) with derivatives of 1,3,4-thiadiazole-2,5-dithiol as new ligands [O] . Al-Nahary Taleb T. 2009

机译：Cr（III），Mn（II），Fe（III），Co（II），Ni（II），Cu（II），Ru（III），Rh（III）和Pd（II）金属配合物的合成和表征）以1,3,4-噻二唑-2,5-二硫醇为新配体
9. Absorption of pyrimidines, purines, and nucleosides by Co, Ni, Cu and Fe /III-montmorillonite /clay-organic studies XIII/ [R] . Brindley, G. W., Lailach, G. E., Thompson, T. D. 1967

机译：通过Co，Ni，Cu和Fe / III-蒙脱土/粘土 - 有机物研究吸收嘧啶，嘌呤和核苷XIII /

Flexible Metal–Porphyrin Dimers (M=Mn III III Cl, Co II II , Ni II II , Cu II II ): Synthesis, Spectroscopy, Electrochemistry, Spectroelectrochemistry, and Theoretical Calculations

摘要

著录项

相似文献

相关主题

期刊订阅