Anthraquinone‐Based Oligomer as a Long Cycle‐Life Organic Electrode Material for Use in Rechargeable Batteries

Yao Masaru; Sano Hikaru; Ando Hisanori; Kiyobayashi Tetsu; Takeichi Nobuhiko

摘要

Abstract > An anthraquinone (AQ)‐based dimer and trimer linked by a triple bond (?C≡C?) were newly synthesized as active materials for the positive electrode of rechargeable lithium batteries. These synthesized oligomers exhibited an initial discharge capacity of about 200?mAh?g ?1 with an average voltage of 2.2–2.3?V versus Li <sub>(C.E.)</sub> . These capacity values are similar to that of the AQ‐monomer, reflecting the two‐electron transfer redox per AQ unit. Regarding their cycling stability, the capacity of the monomer electrode quickly decreased; however, the electrodes of the prepared oligomers showed an improved cycling performance. In particular, the discharge capacities of the trimer remained almost constant for 100 cycles. A theoretical calculation revealed that the intermolecular binding energy can be increased to the level of a weak covalent bonding by oligomerization, which would be beneficial to suppress the dissolution of the organic active materials into the electrolyte solutions. These results show that the cycle‐life of organic active materials can be extended without lowering the discharge capacity by the oligomerization of the redox active molecule unit. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >由三键链接的Anthraquinone（AQ）的anthraquine（aq）的二聚体和三聚体（？c≡ C？）被新合成为可充电锂电池的正电极的活性材料。这些合成的低聚物表现出约200·mAh的初始放电容量为约200？这些容量值类似于AQ单体的容量值，反映每个AQ单元的双电子传输氧化还原。关于其循环稳定性，单体电极的容量迅速降低;然而，制备的低聚物的电极显示出改善的循环性能。特别地，三聚体的放电容量对于100个循环几乎恒定。理论计算表明，通过低聚的分子结合能量可以增加到弱共价键的水平，这将有利于抑制有机活性物质溶解到电解质溶液中的溶解。这些结果表明，通过氧化还原活性分子单元的寡聚化，可以延长有机活性材料的循环寿命而不会降低放电容量。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第7期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yao Masaru&option=202" target="_blank" rel="nofollow">Yao Masaru;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sano Hikaru&option=202" target="_blank" rel="nofollow">Sano Hikaru;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ando Hisanori&option=202" target="_blank" rel="nofollow">Ando Hisanori;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kiyobayashi Tetsu&option=202" target="_blank" rel="nofollow">Kiyobayashi Tetsu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Takeichi Nobuhiko&option=202" target="_blank" rel="nofollow">Takeichi Nobuhiko;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Research Institute of Electrochemical Energy Department of Energy and EnvironmentNational Institute of Advanced Industrial Science and Technology (AIST) 1-8-31 Midorigaoka IkedaOsaka 563-8577 Japan;</p> <p>Research Institute of Electrochemical Energy Department of Energy and EnvironmentNational Institute of Advanced Industrial Science and Technology (AIST) 1-8-31 Midorigaoka IkedaOsaka 563-8577 Japan;</p> <p>Research Institute of Electrochemical Energy Department of Energy and EnvironmentNational Institute of Advanced Industrial Science and Technology (AIST) 1-8-31 Midorigaoka IkedaOsaka 563-8577 Japan;</p> <p>Research Institute of Electrochemical Energy Department of Energy and EnvironmentNational Institute of Advanced Industrial Science and Technology (AIST) 1-8-31 Midorigaoka IkedaOsaka 563-8577 Japan;</p> <p>Research Institute of Electrochemical Energy Department of Energy and EnvironmentNational Institute of Advanced Industrial Science and Technology (AIST) 1-8-31 Midorigaoka IkedaOsaka 563-8577 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium ion battery&option=203" rel="nofollow">lithium ion battery;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=long cycle-life&option=203" rel="nofollow">long cycle-life;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oligomerization&option=203" rel="nofollow">oligomerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organic cathode&option=203" rel="nofollow">organic cathode;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pi-stack interactions&option=203" rel="nofollow">pi-stack interactions;</a> </p> <div class="translation"> 机译：锂离子电池;长循环寿命;寡聚;有机阴极;Pi-Stack相互作用; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022115549.html">Anthraquinone‐Based Oligomer as a Long Cycle‐Life Organic Electrode Material for Use in Rechargeable Batteries</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yao Masaru&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yao Masaru,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sano Hikaru&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sano Hikaru,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ando Hisanori&option=202" 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