Adsorption of Hydrogen Sulfide, Hydrosulfide and Sulfide at Cu(110) ‐ Polarizability and Cooperativity Effects. First Stages of Formation of a Sulfide Layer.

机译：Cu（110） - 极化性和合作效应的吸附硫化氢，氢硫化物和硫化物。形成硫化物层的第一阶段。

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Abstract > Understanding the surface site preference for single adsorbates, the interactions between adsorbates, how these interactions affect surface site specificity in adsorption and perturb the electronic states of surfaces is important for rationalizing the structure of interfaces and the growth of surface products. Herein, using density functional theory (DFT) calculations, we investigated the adsorption of H <sub>2</sub> S, HS and, S onto Cu(110). The surface site specificity observed for single adsorbates can be largely affected by the presence of other adsorbates, especially S that can affect the adsorption of other species even at distances of 13??. The large supercell employed with a surface periodicity of (6×6) allowed us to safely use the Helmholtz method for the determination of the dipole of the surface‐adsorbate complex at low adsorbate coverages. We found that the surface perturbation induced by S can be explained by the charge transfer model, H <sub>2</sub> S leads to a perturbation of the surface that arises mostly from Pauli exclusion effects, whereas HS shows a mix of charge transfer and Pauli exclusion effects. These effects have a large contribution to the long range adsorbate‐adsorbate interactions observed. Further support for the long range adsorbate‐adsorbate interactions are the values of the adsorption energies of adsorbate pairs that are larger than the sum of the adsorption energies of the single adsorbates that constitute the pair. This happens even for large distances and thus goes beyond the H‐bond contribution for the H‐bond capable adsorbate pairs. Exploiting this knowledge we investigated two models for describing the first stages of growth of a layer of S‐atoms at the surface: the formation of islands versus the formation of more homogeneous surface distributions of S‐atoms. We found that for cove </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >了解单个吸附的表面位点偏好，吸附剂之间的相互作用，这些相互作用如何影响表面吸附和扰动的位点特异性表面的电子状态对于合理化界面结构和表面产品的生长是重要的。这里，使用密度官能理论（DFT）计算，我们研究了H <sub> 2 </ sub> s，hs和s的吸附到Cu（110）上。对于单个吸附物观察到的表面位点特异性可以在很大程度上受到其它吸附物的存在的影响，尤其是即使在13Ω的距离中也会影响其他物种的吸附。表面周期性（6×6）采用的大型超级电池允许我们安全地使用Helmholtz方法来确定在低吸附覆盖物中的表面吸附络合物的偶极物。我们发现，S诱导的表面扰动可以通过电荷转移模型来解释，H <sub> 2 </ sub> S导致大多来自Pauli排除效果的表面的扰动，而Hs显示了电荷混合物转移和Pauli排除效果。这些效果对观察到的长距离吸附物 - 吸附相互作用具有很大的贡献。对长距离吸附性 - 吸附相互作用的进一步支持是吸附性对的吸附能量的值，其大于构成该对的单个吸附物的吸附能量的总和。即使是大距离也会发生，因此超出了能够吸附成对的H键的H键贡献。利用这些知识，我们研究了两个模型，用于描述表面上的S-原子层的第一阶段：岛的形成与形成的S-原子的更均匀表面分布。我们发现为湾 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第17期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lousada Cláudio M.&option=202" target="_blank" rel="nofollow">Lousada Cláudio M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Johansson Adam Johannes&option=202" target="_blank" rel="nofollow">Johansson Adam Johannes;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Korzhavyi Pavel A.&option=202" target="_blank" rel="nofollow">Korzhavyi Pavel A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Materials Science and EngineeringKTH Royal Institute of Technology SE-100 44 Stockholm Sweden;</p> <p>Swedish Nuclear Fuel and Waste Management Co. (SKB)Evenemangsgatan 13 Box 3091 169 03 Solna Sweden;</p> <p>Department of Materials Science and EngineeringKTH Royal Institute of Technology SE-100 44 Stockholm Sweden;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=adsorbate-adsorbate interactions&option=203" rel="nofollow">adsorbate-adsorbate interactions;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=copper sulfide growth&option=203" rel="nofollow">copper sulfide growth;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen sulfide&option=203" rel="nofollow">hydrogen sulfide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polarizability&option=203" rel="nofollow">polarizability;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sulfur adsorption&option=203" rel="nofollow">sulfur adsorption;</a> </p> <div class="translation"> 机译：吸附 - 吸附相互作用;硫化铜生长;硫化氢;极化性;硫吸附; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022115212.html">Adsorption of Hydrogen Sulfide, Hydrosulfide and Sulfide at Cu(110) ‐ Polarizability and Cooperativity Effects. 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B. V.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Narayanacharyulu, P. B. 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